Model for the Thermodynamic Properties of a Biodiesel Fuel

被引：101
作者：
Huber, Marcia L. [1 ]
Lemmon, Eric W. [1 ]
Kazakov, Andrei [1 ]
Ou, Lisa S. [1 ]
Bruno, Thomas J. [1 ]
机构：
[1] Natl Inst Stand & Technol, Thermophys Properties Div, Boulder, CO USA
来源：
ENERGY & FUELS | 2009年 / 23卷 / 07期
关键词：
ACID METHYL-ESTERS; DISTILLATION CURVES; PHYSICAL-PROPERTIES; VAPOR-PRESSURES; LIQUID-EQUILIBRIA; FATTY; IMPROVEMENTS; PALMITATE; EQUATIONS; STATE;
D O I：
10.1021/ef900159g
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
We present an equation-of-state approach to modeling the thermodynamic properties of a biodiesel fuel. Preliminary Helmholtz-type equations of state were developed with limited experimental data for live fatty acid methyl esters (FAMEs) that are the primary constituents of soy-based biodiesel fuel, namely, methyl palmitate, methyl stearate, methyl oleate, methyl linoleate, and methyl linolenate. These components Were combined in a mixture model using ideal mixing to represent the thermodynamic properties of a biodiesel fuel. We performed limited experimental measurements on the density, sound speed. and initial boiling point of two biodiesel fuel samples and compared the results with the model.
引用
收藏
页码：3790 / 3797
页数：8
相关论文
共 92 条
[1]  
Albert O, 1938, Z PHYS CHEM A-CHEM T, V182, P421
[2]   REFRACTIVE INDICES OF THE METHYL, PROPYL, AND ISOPROPYL ESTERS OF THE C6 - C18 SATURATED FATTY ACIDS FOR VARIOUS TEMPERATURES BETWEEN 20 AND 45-DEGREES-C [J].
ALTHOUSE, PM ;
HUNTER, GW ;
TRIEBOLD, HO .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1947, 24 (08) :257-259
[3]  
[Anonymous], CRC HDB BASIC TABLES
[4]  
*ASTM, 2008, BOOK STAND
[5]  
BOELHOUWER JWM, 1950, APPL SCI RES, V2, P249
[6]   ESTERS OF NATURALLY OCCURRING FATTY ACIDS - PHYSICAL PROPERTIES OF METHYL, PROPYL, AND ISOPROPYL ESTERS OF C-6 TO C-18 SATURATED FATTY ACIDS [J].
BONHORST, CW ;
ALTHOUSE, PM ;
TRIEBOLD, HO .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1948, 40 (12) :2379-2384
[7]   Volume-temperature-pressure relations for several non-volatile liquids. [J].
Bridgman, PW .
PROCEEDINGS OF THE AMERICAN ACADEMY OF ARTS AND SCIENCES, 1932, 67 (1/11) :1-27
[8]  
Bruno T.J.a.S., 2005, CRC HDB FUNDAMENTAL
[9]   Improvements in the measurement of distillation curves. 1. A composition-explicit approach [J].
Bruno, TJ .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (12) :4371-4380
[10]   Improvements in the measurement of distillation curves. 2. Application to aerospace/aviation fuels RP-1 and s-8 [J].
Bruno, TJ ;
Smith, BL .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (12) :4381-4388
12345678910