Efficient preparation of aldoximes from arylaidehydes, ethylenediamine and Oxone® in water

被引：20

作者：

Xia, Jing-Jing

Wang, Guan-Wu ^{[1
]}

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

来源：

MOLECULES | 2007年 / 12卷 / 02期

关键词：

aldoximes; aryl aldehydes; ethylenediamine; Oxone((R)); water;

D O I：

10.3390/12020231

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The one-pot reaction of aromatic aldehydes, ethylenediamine and Oxone((R)) (2KHSO(5)center dot KRSO4 center dot K2SO4) in pure water was found to unexpectedly afford aldoximes in excellent yields.

引用

页码：231 / 236

页数：6

共 34 条

[1] Synthesis and structure of bifunctional N-alkylbenzimidazole phenylboronate derivatives [J].

Blatch, Alexandrea J. ;

Chetina, Olga V. ;

Howard, Judith A. K. ;

Patrick, Leonard G. F. ;

Smethurst, Christian A. ;

Whiting, Andrew .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (17) :3297-3302

[2] ALKYLATION OF SYN- AND ANTI-BENZALDOXIMES [J].

BUEHLER, E .

JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (02) :261-&

[3] CHLORINATION OF OXIMES .1. REACTION AND MECHANISM OF CHLORINATION OF OXIMES IN COMMERCIAL CHLOROFORM AND METHYLENE CHLORIDE [J].

CHIANG, YH .

JOURNAL OF ORGANIC CHEMISTRY, 1971, 36 (15) :2146-&

[4] ISOMERIZATION OF ALDOXIMES TO AMIDES UNDER SUBSTANTIALLY NEUTRAL CONDITIONS [J].

FIELD, L ;

MARSHALL, WS ;

SHUMAKER, SH ;

HUGHMARK, PB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (08) :1983-&

[5] A mild and efficient one-pot synthesis of 2-dihydroimidazoles from aldehydes [J].

Fujioka, H ;

Murai, K ;

Ohba, Y ;

Hiramatsu, A ;

Kita, Y .

TETRAHEDRON LETTERS, 2005, 46 (13) :2197-2199

[6]

GATTERMANN L, 2006, JLIEBIGS ANN CHEM, P347

[7] An efficient and one-pot synthesis of imidazolines and benzimidazoles via anaerobic oxidation of carbon-nitrogen bonds in water [J].

Gogol, P ;

Konwar, D .

TETRAHEDRON LETTERS, 2006, 47 (01) :79-82

[8] A rapid and convenient synthesis of oximes in dry media under microwave irradiation [J].

Hajipour, AR ;

Mallakpour, SE ;

Imanzadeh, G .

JOURNAL OF CHEMICAL RESEARCH, 1999, (03) :228-229

[9] SELECTIVE CATALYTIC-OXIDATION OF BENZYLIC AND ALLYLIC AMINES TO OXIMES WITH H2O2 OVER TS-1 [J].

JOSEPH, R ;

RAVINDRANATHAN, T ;

SUDALAI, A .

TETRAHEDRON LETTERS, 1995, 36 (11) :1903-1904

[10] Organic reactions in aqueous media with a focus on carbon-carbon bond formations: A decade update [J].

Li, CJ .

CHEMICAL REVIEWS, 2005, 105 (08) :3095-3165

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