Synthesis, structural characterization, and spectroscopy of the cadmium-cadmium bonded molecular species Ar′CdCdAr′ (Ar′ = C6H3-2,6-(C6H3-2,6-Pri2)2)

被引：50

作者：

Zhu, Zhongliang ^{[1
]}

Fischer, Roland C. ^{[1
]}

Fettinger, James C. ^{[1
]}

Rivard, Eric ^{[1
]}

Brynda, Marcin ^{[1
]}

Power, Philip P. ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 47期

关键词：

D O I：

10.1021/ja066108h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and first structural characterization of a cadmium-cadmium bonded molecular compound Ar-CdCdAr- (Ar- = C6H3-2,6-(C6H3-2,6-Pri2)2) are reported. The existence of the Cd-Cd bond was established by 113Cd NMR spectroscopy and X-ray diffraction (Cd-Cd = 2.6257(5) Å). Like its group 12 analogue Ar-ZnZnAr-, DFT calculations showed that Ar-CdCdAr- had significant p-character in the Cd-Cd σ-bonding HOMO. Copyright © 2006 American Chemical Society.

引用

页码：15068 / 15069

页数：2

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