One-pot synthesis of sorbitol via hydrolysis-hydrogenation of cellulose in the presence of Ru-containing composites

被引：27
作者：
Gromov, Nikolay V. [1 ,2 ]
Medvedeva, Tatiana B. [1 ]
Rodikova, Yulia A. [1 ]
Timofeeva, Maria N. [1 ,2 ]
Panchenko, Valentina N. [1 ,2 ]
Taran, Oxana P. [1 ,3 ]
Kozhevnikov, Ivan V. [4 ]
Parmon, Valentin N. [1 ]
机构：
[1] Boreskov Inst Catalysis SB RAS, Lavrentiev Ave 5, Novosibirsk 630090, Russia
[2] Novosibirsk State Tech Univ, Karl Marx Ave 20, Novosibirsk 630092, Russia
[3] FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, Akademgorodok 50-24, Krasnoyarsk 660036, Russia
[4] Univ Liverpool, Liverpool, Merseyside, England
来源：
BIORESOURCE TECHNOLOGY | 2021年 / 319卷 / 319期
基金：
俄罗斯基础研究基金会;
关键词：
Cellulose; Sorbitol; One-pot hydrolysis-hydrogenation; Ruthenium; Composites based on heteropoly acids and oxides; SOLID ACID; CATALYTIC CONVERSION; GLUCOSE;
D O I：
10.1016/j.biortech.2020.124122
中图分类号：
S2 [农业工程];
学科分类号：
0828 ;
摘要：
The aim of this work was to study the one-pot synthesis of sorbitol via hydrolysis-hydrogenation of cellulose in the presence of Ru-containing composites based on H3PW12O40 supported on ZrO2 and Nb2O5 (Ru-PW/ZrO2 and Ru-PW/Nb2O5). The main parameters impacted the reaction rate and yield of sorbitol, i.e. reaction conditions and type of catalyst were investigated. Ru-PW/ZrO2 systems were more active than Ru-PW/Nb2O5. The yield of sorbitol was found to depend on the activation temperature of PW/ZrO2 and PWNb2O5 which affected textural properties, the amount of acid sites and size of Ru nanoparticles. The highest 66% sorbitol yield was observed in the presence of 3%Ru-PW/ZrO2 activated at 550 degrees C and 1/1 of weight ratio of cellulose/catalyst, 180 degrees C, 7 MPa hydrogen pressure. This catalyst was stable for three cycles of the reaction without lost of it's activity.
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页数：7
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