Design and characterization of a recirculating liquid-microjet photoelectron spectrometer for multiphoton ultraviolet photoelectron spectroscopy

被引：19
作者：
Riley, Jamie W. [1 ]
Wang, Bingxing [1 ,2 ]
Parkes, Michael A. [1 ]
Fielding, Helen H. [1 ]
机构：
[1] UCL, Dept Chem, 20 Gordon St, London WC1H 0AJ, England
[2] Henan Inst Sci & Technol, Coll Chem & Chem Engn, Eastern Hualan Ave, Xinxiang 453003, Henan, Peoples R China
来源：
REVIEW OF SCIENTIFIC INSTRUMENTS | 2019年 / 90卷 / 08期
基金：
英国工程与自然科学研究理事会;
关键词：
SOLVATED ELECTRONS; BULK WATER; IONIZATION; DYNAMICS; PHOTOEMISSION; RELAXATION; METHANOL; MOLECULES; ENERGIES; SPECTRA;
D O I：
10.1063/1.5099040
中图分类号：
TH7 [仪器、仪表];
学科分类号：
0804 ; 080401 ; 081102 ;
摘要：
A new recirculating liquid-microjet photoelectron spectrometer for multiphoton ultraviolet photoelectron spectroscopy is described. A recirculating system is essential for studying samples that are only available in relatively small quantities. The reduction in background pressure when using the recirculating system compared to a liquid-nitrogen cold-trap results in a significant improvement in the quality of the photoelectron spectra. Moreover, the recirculating system results in a negligible streaming potential. The instrument design, operation, and characterization are described in detail, and its performance is illustrated by comparing a photoelectron spectrum of aqueous phenol recorded using the recirculating system with one recorded using a liquid nitrogen cold-trap. Published under license by AIP Publishing.
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页数：10
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