Phase transitions in oxides, fluorides and oxyfluorides with the ordered perovskite structure

被引:7
作者
Flerov, I. N. [1 ]
Gorev, M. V. [1 ]
Fokina, V. D. [1 ]
Molokeev, M. S. [1 ]
机构
[1] RAS, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
关键词
phase transitions; ordered perovskites; entropy; electron density;
D O I
10.1080/00150190601180364
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Some results of calorimetric and structural investigations of the A(2)A'MOxF6-x crystals series with the elpasolite-cryolite structure are reported. The analysis has exhibited a key role of the MOxF6-x species content in the disordering degree and stability of Fm(3)m phase as well as in the nature of structural distortions.
引用
收藏
页码:77 / 83
页数:7
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