Derivatives of (S)-{[2-(methoxymethyl)pyrrolidin-1-yl]-methyl}ferrocene -: New planar chiral ligands

被引：3

作者：

Sebesta, R ^{[1
]}

Salisová, M ^{[1
]}

机构：

[1] Comenius Univ, Fac Nat Sci, Dept Organ Chem, Bratislava 84215, Slovakia

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2002年 / 67卷 / 11期

关键词：

amino alcohols; ferrocenes; metallocenes; ferrocenyl ligands; planar chirality; asymmetric catalysis; diethylzinc addition;

D O I：

10.1135/cccc20021700

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New planar chiral amino-alcohol ferrocene ligands based on (S)-2-(methoxymethyl) pyrrolidine were synthesized and employed in the enantioselective addition of diethylzinc to benzaldehyde with enantioselectivity up to 82%. The effect of planar chirality was evaluated.

引用

页码：1700 / 1708

页数：9

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