First examples of the selective carbonylation of C6-C10 linear alkanes to tertiary carbonyl-containing compounds

被引：7

作者：

Akhrem, IS ^{[1
]}

Afanas'eva, LV ^{[1
]}

Vitt, SV ^{[1
]}

Petrovskii, PV ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2002年 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1070/MC2002v012n05ABEH001661

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The carbonylation of C-6-C-10 n-alkanes with CO in the presence of CBr4.2AlBr3 at -40 degreesC and 1 atm CO leads to the products of non-destructive carbonylation, i.e., the esters of tertiary carboxylic acids, (RC)-C-1(Me)(2)COOR and R-2(Et)C(Me)COOR, after the workup, of reaction mixtures with ROH.

引用

页码：180 / 182

页数：3

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