Inhibition of C-steel Corrosion by Green Tea Extract in Hydrochloric Solution

被引:40
作者
Salghi, R. [1 ]
Jodeh, S. [2 ]
Ebenso, Eno E. [2 ,3 ]
Lgaz, H. [1 ]
Ben Hmamou, D. [1 ]
Belkhaouda, M. [1 ]
Ali, I. H. [4 ]
Messali, M. [5 ]
Hammouti, B. [6 ]
Fattouch, S. [7 ]
机构
[1] Univ Ibn Zohr, ENSA, Lab Appl Chem & Environm, POB 1136, Agadir, Morocco
[2] An Najah Natl Univ, Dept Chem, POB 7, Nablus, Palestine
[3] North West Univ Mafikeng Campus, Fac Agr Sci & Technol, Mat Sci Innovat & Modelling MaSIM Res Focus Area, Private Bag X2046, ZA-2735 Mmabatho, South Africa
[4] King Khalid Univ, Coll Sci, Chem Dept, Abha, Saudi Arabia
[5] Taibah Univ, Fac Sci, Chem Dept, Al Madinah Al Mounawwara 30002, Saudi Arabia
[6] Univ Mohammed Premier, Fac Sci, LCAE URAC 18, POB 717, Oujda 60000, Morocco
[7] Univ Carthage, INSAT, LIP MB, Tunis, Tunisia
来源
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2017年 / 12卷 / 04期
关键词
Inhibition; Corrosion; Green Tea Extract; Steel; COLD-ROLLED STEEL; MILD-STEEL; CARBON-STEEL; ACID SOLUTION; THERMODYNAMIC PROPERTIES; ADSORPTION; DERIVATIVES; IRON;
D O I
10.20964/2017.04.46
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Inhibition ability of green tea extract (GTE) on the C38 steel (CS) in 1.0 M HCl was evaluated using different methods such as: weight loss, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP) methods at various temperatures. Polarisation curves show that GTE acts essentially as mixed-type inhibitor controlling cathodic and anodic reactions with slight predominant in cathodic branches. EIS results indicate the increase of resistance transfer (R-t) while double layer capacitance (C-dl) decrease in the rise of green tea extract (GTE) concentrations. Obtained results also showed that the inhibition efficiency decreased with a rise in the temperature. Activation energy (E-a), enthalpy (Delta H-a*) and entropy and (Delta S-a*) of corrosion process were estimated using experimental measurements.
引用
收藏
页码:3283 / 3295
页数:13
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