Experimental study on NO oxidation by K2S2O8 + Fe(II)EDTA

被引：9

作者：

Hu, Hui ^{[1
]}

Huang, Hao ^{[1
]}

Tao, Gong-Kai ^{[1
]}

Xie, Jing ^{[2
]}

Yang, Cheng ^{[3
]}

Huang, Ting ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Sch Environm Sci & Engn, Wuhan 430074, Peoples R China

[2] China Univ Geosci, Fac Mat Sci & Chem, Wuhan 430074, Peoples R China

[3] Tsinghua Univ, Grad Sch Shenzhen, Key Lab Microorganism Applicat & Risk Control She, Shenzhen, Peoples R China

来源：

CHEMICAL PHYSICS LETTERS | 2017年 / 678卷

基金：

中国国家自然科学基金;

关键词：

Potassium persulfate; Fe(II)EDTA; Denitrification; Wet oxidation; FLUE-GAS; NITRIC-OXIDE; SIMULTANEOUS ABSORPTION; SIMULTANEOUS REMOVAL; SODIUM PERSULFATE; AQUEOUS-SOLUTIONS; FENTON REAGENT; KINETICS; SO2; MECHANISM;

D O I：

10.1016/j.cplett.2017.04.029

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

NO absorption and oxidation by K2S2O8 + Fe(II)EDTA system was studied in a lab-scale bubble reactor. The effects of different additives, reaction temperatures, pH values, K2S2O8 and Fe(II)EDTA concentrations on NO conversion were systematic investigated. Results indicated that NO conversion rate of K2S2O8 + Fe (II)EDTA system increased to 91.6% when concentrations of K2S2O8 and Fe(II)EDTA were both 30 mmol/L at 80 degrees C. NO conversion rate was positively correlated with the SO42- concentration in absorption solution, and it kept around 80% in a wide pH range, which made this technology to be a promising method for the denitrification of coal-fired flue gas. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：23 / 27

页数：5

共 23 条

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