Direct catalytic oxidation of cyclohexene to 1, 2-cyclohexanediol by aqueous hydrogen peroxide under solvent-free condition

被引：6

作者：

Zhang, Aiping ^{[1
,2
]}

Gao, Shuang ^{[1
]}

Lv, Ying ^{[1
]}

Xi, Zuwei ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2009年 / 35卷 / 05期

关键词：

Cyclohexene; Epoxidation; Heteropolyphosphatotungstate; Hydrogen peroxide; PHASE-TRANSFER CATALYSIS; EPOXIDATION;

D O I：

10.1007/s11164-009-0068-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclohexene can be oxidized directly to 1, 2-cyclohexanediol with aqueous hydrogen peroxide under solvent-free condition using a heteropolyphosphatotungstate catalyst. And an isolated yield of 54% was obtained in this catalytic system.

引用

页码：563 / 571

页数：9

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