Direct catalytic oxidation of cyclohexene to 1, 2-cyclohexanediol by aqueous hydrogen peroxide under solvent-free condition

被引：6
|
作者：
Zhang, Aiping [1 ,2 ]
Gao, Shuang [1 ]
Lv, Ying [1 ]
Xi, Zuwei [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2009年 / 35卷 / 05期
关键词：
Cyclohexene; Epoxidation; Heteropolyphosphatotungstate; Hydrogen peroxide; PHASE-TRANSFER CATALYSIS; EPOXIDATION;
D O I：
10.1007/s11164-009-0068-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cyclohexene can be oxidized directly to 1, 2-cyclohexanediol with aqueous hydrogen peroxide under solvent-free condition using a heteropolyphosphatotungstate catalyst. And an isolated yield of 54% was obtained in this catalytic system.
引用
收藏
页码：563 / 571
页数：9
相关论文
共 50 条
  • [31] 12-Tungstocobaltate(II) catalyzed selective oxidation of sulfides to sulfoxides using aqueous hydrogen peroxide under solvent free conditions
    Amit R. Supale
    Gavisiddappa S. Gokavi
    Reaction Kinetics and Catalysis Letters, 2009, 96 : 83 - 89
  • [32] 12-Tungstocobaltate(II) catalyzed selective oxidation of sulfides to sulfoxides using aqueous hydrogen peroxide under solvent free conditions
    Supale, Amit R.
    Gokavi, Gavisiddappa S.
    REACTION KINETICS AND CATALYSIS LETTERS, 2009, 96 (01): : 83 - 89
  • [33] Heterometallic CuII/LnIII polymers active in the catalytic aerobic oxidation of cycloalkenes under solvent-free conditions
    Cancino, P.
    Santibanez, L.
    Fuentealba, P.
    Olea, C.
    Vega, A.
    Spodine, E.
    DALTON TRANSACTIONS, 2018, 47 (38) : 13360 - 13367
  • [34] Strategies for tuning the catalytic activity of zinc complexes in the solvent-free coupling reaction of CO2 and cyclohexene oxide
    Biagini, Paolo
    Perego, Carlo
    Po, Riccardo
    Boggioni, Laura
    Cozzolino, Mariachiara
    Losio, Simona
    Flamigni, Agnese
    Colombo, Alessia
    Dragonetti, Claudia
    Fagnani, Francesco
    Matozzo, Paola
    Roberto, Dominique
    Inorganica Chimica Acta, 2022, 532
  • [35] Solvent-free benzylic oxidations using urea-hydrogen peroxide complex (UHP) under microwave irradiation
    Paul, S
    Nanda, P
    Gupta, R
    SYNLETT, 2004, (03) : 531 - 533
  • [36] Strategies for tuning the catalytic activity of zinc complexes in the solvent-free coupling reaction of CO2 and cyclohexene oxide
    Biagini, Paolo
    Perego, Carlo
    Po, Riccardo
    Boggioni, Laura
    Cozzolino, Mariachiara
    Losio, Simona
    Flamigni, Agnese
    Colombo, Alessia
    Dragonetti, Claudia
    Fagnani, Francesco
    Matozzo, Paola
    Roberto, Dominique
    INORGANICA CHIMICA ACTA, 2022, 532
  • [37] Solvent-free chemoselective oxidation of alcohols by hydrogen peroxide using a new synthesized copper complex as reusable heterogeneous nanocatalyst
    S. Saeednia
    M. Hatefi Ardakani
    Z. Pakdin-Parizi
    P. Iranmanesh
    S. Sinaei
    Journal of the Iranian Chemical Society, 2016, 13 : 1963 - 1975
  • [38] Solvent-free oxidation of alcohols by hydrogen peroxide over chromium Schiff base complexes immobilized on MCM-41
    Xiaoli Wang
    Gongde Wu
    Wei Wei
    Yuhan Sun
    Transition Metal Chemistry, 2010, 35 : 213 - 220
  • [39] Solvent-free oxidation of alcohols by hydrogen peroxide over chromium Schiff base complexes immobilized on MCM-41
    Wang, Xiaoli
    Wu, Gongde
    Wei, Wei
    Sun, Yuhan
    TRANSITION METAL CHEMISTRY, 2010, 35 (02) : 213 - 220
  • [40] Tetraneopentyltitanium derived supported catalysts - Part 1. Synthesis and catalytic properties for the epoxidation of cyclohexene with aqueous hydrogen peroxide
    Holmes, SA
    Quignard, F
    Choplin, A
    Teissier, R
    Kervennal, J
    JOURNAL OF CATALYSIS, 1998, 176 (01) : 173 - 181
12345