Direct catalytic oxidation of cyclohexene to 1, 2-cyclohexanediol by aqueous hydrogen peroxide under solvent-free condition

被引：6
|
作者：
Zhang, Aiping [1 ,2 ]
Gao, Shuang [1 ]
Lv, Ying [1 ]
Xi, Zuwei [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2009年 / 35卷 / 05期
关键词：
Cyclohexene; Epoxidation; Heteropolyphosphatotungstate; Hydrogen peroxide; PHASE-TRANSFER CATALYSIS; EPOXIDATION;
D O I：
10.1007/s11164-009-0068-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cyclohexene can be oxidized directly to 1, 2-cyclohexanediol with aqueous hydrogen peroxide under solvent-free condition using a heteropolyphosphatotungstate catalyst. And an isolated yield of 54% was obtained in this catalytic system.
引用
收藏
页码：563 / 571
页数：9
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