NMR 1H, 13C, 31P Interpretation of Phosphorylotropic Rearrangement in N,N′-(Bis)(Diizopropoxyphosphorylamidocarbonyl)-1,10-Diaza-18-Crown-6-Ester in DMSO Solution

被引：2

作者：

Karataeva, F. Kh. ^{[1
]}

Efimov, S. V. ^{[1
]}

Klochkov, V. V. ^{[1
]}

机构：

[1] Kazan Fed Univ, Kazan 420008, Russia

来源：

BIONANOSCIENCE | 2019年 / 9卷 / 04期

基金：

俄罗斯科学基金会;

关键词：

NMR spectroscopy; 1; 10-diaza-18-crown-6-ester; Phosphorylotropic rearrangement; Temperature changes; Solvent effect; INTRAMOLECULAR LABILITY; N-(THIO)PHOSPHORYL(THIO)AMIDES;

D O I：

10.1007/s12668-019-00674-4

中图分类号：

TB3 [工程材料学]; R318.08 [生物材料学];

学科分类号：

0805 ; 080501 ; 080502 ;

摘要：

Phosphorylotropic rearrangement in N,N '-(bis)(diizopropoxyphosphorylamidocarbonyl)-1,10-diaza-18-crown-6-ester dissolved in DMSO was investigated by H-1, C-13, and P-31 NMR spectroscopy. The transition from the amide form to the phosphorylotropic form was shown to cause a simultaneous signal modification of the NMR spectra of three mentioned isotopes in all structural elements of the molecule.

引用

页码：859 / 861

页数：3