A modified sequential deposition method for fabrication of perovskite solar cells

被引:38
作者
Li, Hangqian [1 ]
Li, Shibin [1 ]
Wang, Yafei [1 ]
Sarvari, Hojjatollah [2 ,3 ]
Zhang, Peng [1 ]
Wang, Meijuan [1 ]
Chen, Zhi [1 ,2 ,3 ]
机构
[1] Univ Elect Sci & Technol China, Sch Optoelect Informat, Chengdu 610054, Peoples R China
[2] Univ Kentucky, Dept Elect & Comp Engn, Lexington, KY 40506 USA
[3] Univ Kentucky, Ctr Nanoscale Sci & Engn, Lexington, KY 40506 USA
基金
中国国家自然科学基金;
关键词
Perovskite solar cell; Capping layer; Pre-coating; Modified sequential deposition; HIGH-PERFORMANCE; HALIDE PEROVSKITES; CHARGE-TRANSPORT; EFFICIENT; CH3NH3PBI3; MORPHOLOGY; GROWTH; FILMS;
D O I
10.1016/j.solener.2015.12.045
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this paper, the important role of perovskites capping layers in the compact-TiO2/mesoporous-TiO2/CH3NH3PbI3/HTM/Au solar cells was investigated. The capping layers were prepared by controlling the concentration of PbI2 solutions, pre-coating in CH3NH3I solution, the reaction temperature, and the dipping time in the sequential deposition process. The results of X-ray diffraction (XRD) spectra revealed that there was no PbI2 remains observed in the perovskite crystal structure, indicating that PbI2 was converted into CH3NH3PbI3 completely. The morphologies of the capping layers are studied by scanning electron microscopy (SEM). Furthermore, organic-inorganic hybrid perovskite solar cells fabricated using the continuous and compact perovskite capping layers exhibit power conversion efficiency of 12.9% and photocurrents up to 19.4 mA cm(-2). (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:243 / 251
页数:9
相关论文
共 50 条
  • [21] Fabrication processes for all-inorganic CsPbBr3 perovskite solar cells
    Park, Jin Ho
    Yoon, Young Seon
    Kim, Jin Young
    ECOMAT, 2023, 5 (11)
  • [22] Modified Antisolvent Method for Improving the Performance and Stability of Triple-Cation Perovskite Solar Cells
    Samadpour, Mahmoud
    Golchini, Arezo
    Abdizadeh, Karim
    Heydari, Mahsa
    Forouzandeh, Mozhdeh
    Saki, Zahra
    Taghavinia, Nima
    ACS OMEGA, 2021, 6 (01): : 172 - 179
  • [23] Continuous dripping method as a deposition route for highperformance mesoporous perovskite solar cells
    Chen, Guo
    Zheng, Lingling
    Zhang, Fengyan
    8TH INTERNATIONAL CONFERENCE ON APPLIED ENERGY (ICAE2016), 2017, 105 : 5067 - 5072
  • [24] Metal halide perovskite solar cells by modified chemical vapor deposition
    Qiu, Longbin
    He, Sisi
    Jiang, Yan
    Qi, Yabing
    JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (40) : 22759 - 22780
  • [25] Humidity-Tolerant Roll-to-Roll Fabrication of Perovskite Solar Cells via Polymer-Additive-Assisted Hot Slot Die Deposition
    Kim, Jueng-Eun
    Kim, Seok-Soon
    Zuo, Chuantion
    Gao, Mei
    Vak, Doojin
    Kim, Dong-Yu
    ADVANCED FUNCTIONAL MATERIALS, 2019, 29 (26)
  • [26] Trihydrazine Dihydriodide-Assisted Fabrication of Efficient Formamidinium Tin Iodide Perovskite Solar Cells
    Li, Fengzhu
    Fan, Haochen
    Zhang, Jie
    Huang, Jin-Hua
    Wang, Pengcheng
    Gao, Caiyan
    Yang, Lian-Ming
    Zhu, Zonglong
    Jen, Alex K-Y
    Song, Yanlin
    Jiang, Ke-Jian
    SOLAR RRL, 2019, 3 (09)
  • [27] Fabrication and characterization of perovskite type solar cells using phthalocyanine complexes
    Suzuki, Atsushi
    Okumura, Hiroki
    Yamasaki, Yasuhiro
    Oku, Takeo
    APPLIED SURFACE SCIENCE, 2019, 488 : 586 - 592
  • [28] Sequential Slot-Die Deposition of Perovskite Solar Cells Using Dimethylsulfoxide Lead Iodide Ink
    Burkitt, Daniel
    Searle, Justin
    Worsley, David A.
    Watson, Trystan
    MATERIALS, 2018, 11 (11):
  • [29] Pre-crystallisation applied in sequential deposition approaches to improve the photovoltaic performance of perovskite solar cells
    Zhang, Yulong
    Jiang, Zhaoyi
    Zhang, Weijia
    Yan, Lanqin
    Lu, Chaoqun
    Ni, Cong
    JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 832
  • [30] Self-Assembly of Perovskite for Fabrication of Semitransparent Perovskite Solar Cells
    Aharon, Sigalit
    Layani, Michael
    Cohen, Bat-El
    Shukrun, Efrat
    Magdassi, Shlomo
    Etgar, Lioz
    ADVANCED MATERIALS INTERFACES, 2015, 2 (12):