One- and two-photon absorption in transition metal oxide glasses

被引：24
作者：
El-Diasty, Fouad [1 ]
Abdel-Baki, Manal [2 ]
机构：
[1] Ain Shams Univ, Dept Phys, Fac Sci, Cairo 11566, Egypt
[2] Natl Res Ctr, Dept Glass, Cairo 12311, Egypt
来源：
JOURNAL OF APPLIED PHYSICS | 2009年 / 106卷 / 05期
关键词：
absorption coefficients; aluminium compounds; barium compounds; bismuth compounds; bond lengths; borate glasses; chromium compounds; energy gap; glass; lithium compounds; magnesium compounds; polarisability; silicon compounds; sodium compounds; titanium compounds; two-photon processes; NONLINEAR-OPTICAL-PROPERTIES; EDGE; DEPENDENCE; DISPERSION; SILICATE;
D O I：
10.1063/1.3213378
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Scaling of nonlinear two-photon absorption to optical bandgap (which describes the electronic structure of material) in transition metal glasses is given through a proposed empirical equation. A wide applicability of the relation is proven through the 21 studied glasses. The relationship between the calculated nonlinear absorption coefficient and the measured bandgap energy using Tauc's parabolic band model is discussed in terms of electronic structure of constituent oxides, ionic polarizability, hyperpolarizability of cations, nonbridging oxygen bonds, and the cationic bond-length approach.
引用
收藏
页数：4
相关论文
共 34 条
[1]   Optical characterization of xTiO2-(60-x)SiO2-40Na2O glasses:: II.: Absorption edge, Fermi level, electronic polarizability and optical basicity [J].
Abdel-Baki, M ;
El-Diasty, F ;
Wahab, FAA .
OPTICS COMMUNICATIONS, 2006, 261 (01) :65-70
[2]  
Abdel-Baki M, 2007, PHYS CHEM GLASSES-B, V48, P74
[3]   Factors affecting optical dispersion in borate glass systems [J].
Abdel-Baki, Manal ;
Abdel-Wahab, F. A. ;
Radi, Amr ;
El-Diasty, Fouad .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2007, 68 (08) :1457-1470
[4]   RDF analysis, positron annihilation and Raman spectroscopy of xTiO2-(60-x)SiO2-40Na2O non-linear optical glasses:: III.: Non-bridging oxygen bonds tracing and structure analysis [J].
Abou Sharma, A. ;
El Keriem, M. S. Abd ;
Abdel-Baki, Manal ;
El-Diasty, Fouad .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2007, 353 (28) :2708-2716
[5]   White-light continuum Z-scan technique for nonlinear materials characterization [J].
Balu, M ;
Hales, J ;
Hagan, DJ ;
Van Stryland, EW .
OPTICS EXPRESS, 2004, 12 (16) :3820-3826
[6]   RECENT ADVANCES IN NONLINEAR OPTICAL AND ELECTROOPTICAL MATERIALS [J].
CHEN, CT ;
LIU, GZ .
ANNUAL REVIEW OF MATERIALS SCIENCE, 1986, 16 :203-243
[7]   CONDUCTION IN NON-CRYSTALLINE SYSTEMS .5. CONDUCTIVITY, OPTICAL ABSORPTION AND PHOTOCONDUCTIVITY IN AMORPHOUS SEMICONDUCTORS [J].
DAVIS, EA ;
MOTT, NF .
PHILOSOPHICAL MAGAZINE, 1970, 22 (179) :903-&
[8]   Z-scan measurements using femtosecond continuum generation [J].
De Boni, L ;
Andrade, AA ;
Misoguti, L ;
Mendonça, CR ;
Zilio, SC .
OPTICS EXPRESS, 2004, 12 (17) :3921-3927
[9]   2-PHOTON LASER SCANNING FLUORESCENCE MICROSCOPY [J].
DENK, W ;
STRICKLER, JH ;
WEBB, WW .
SCIENCE, 1990, 248 (4951) :73-76
[10]   Optical band gap studies on lithium aluminum silicate glasses doped with Cr3+ ions [J].
El-Diasty, Fouad ;
Wahab, Fathy A. Abdel ;
Abdel-Baki, Manal .
JOURNAL OF APPLIED PHYSICS, 2006, 100 (09)
1234