Isolable vinylgold intermediates - first access to phantoms of homogeneous gold catalysis

被引：56
|
作者：
Hashmi, A. Stephen K. [1 ]
机构：
[1] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany
来源：
GOLD BULLETIN | 2009年 / 42卷 / 04期
关键词：
Palladium; Alkyne; Crystal Structure Analysis; Oxazolines; Dppf;
D O I：
10.1007/BF03214949
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
For more than a decade vinylgold(I) compounds were written as intermediates in gold-catalysed reactions of alkynes and allenes, but only now the experimental proof for their participation in catalytic cycles could be obtained. This includes preparative access to these species, which for the first time allows to expand this aspect of organogold chemistry in new directions.
引用
收藏
页码：275 / 279
页数：5
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