Stereoselective Restructuring of 3-Arylcyclobutanols into 1-Indanols by Sequential Breaking and Formation of Carbon-Carbon Bonds

被引：100
作者：
Shigeno, Masanori [1 ]
Yamamoto, Taiga [1 ]
Murakami, Masahiro [1 ]
机构：
[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2009年 / 15卷 / 47期
基金：
日本学术振兴会;
关键词：
1,2-addition; asymmetric synthesis; C-C activation; indanols; rhodium; RHODIUM-CATALYZED ADDITION; ENANTIOSELECTIVE CONSTRUCTION; ASYMMETRIC-SYNTHESIS; TERTIARY ALCOHOLS; H ACTIVATION; PALLADIUM; CLEAVAGE; CENTERS; STEREOCENTERS; MOLECULES;
D O I：
10.1002/chem.200902593
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
On the contrary! A rhodium-catalyzed restructuring reaction of 3-arylcyclobutanols to 1-indanols is reported, in which two chiral quaternary carbon centers are formed in a highly enantioselective fashion by a sequence of two contradictory elementary steps, that is, carbon-carbon bond cleavage and carbon-carbon bond formation. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：12929 / 12931
页数：3
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