Chiral discrimination of α-amino acids with a C2-symmetric homoditopic receptor

被引：43

作者：

Sambasivan, Sunderraman

Kim, Dae-sik

Ahn, Kyo Han ^{[1
]}

机构：

[1] POSTECH, Dept Chem, Pohang 790784, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 04期

关键词：

ENANTIOSELECTIVE FLUORESCENT RECOGNITION; MOLECULAR RECOGNITION; DERIVATIVES; COMPLEXATION; ALCOHOLS; ANIONS;

D O I：

10.1039/b919957h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral discrimination of alpha-amino acids has been realized by a C-2-symmetric homoditopic receptor, which is based on a binaphthyl chiral skeleton with 2,2'-diisopropoxy substituents and a common binding side arm, (o-carboxamido)-trifluoro-acetophenone moiety, in the 3,3'-positions, which recognizes alpha-amino acids as their amino carboxylate forms through formation of stabilized adducts.

引用

收藏

页码：541 / 543

页数：3

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