In situ impedance spectroscopy study of the electrochemical corrosion of Ti and Ti-6Al-4V in simulated body fluid at 25 °C and 37 °C

被引:250
作者
Alves, V. A. [1 ]
Reis, R. Q. [2 ]
Santos, I. C. B. [2 ]
Souza, D. G. [2 ]
Goncalves, T. de F. [3 ]
Pereira-da-Silva, M. A. [4 ,5 ]
Rossi, A. [1 ]
da Silva, L. A. [1 ]
机构
[1] Univ Fed Triangulo Mineiro, Inst Educ, Curso Licenciatura Quim, BR-38025440 Uberaba, MG, Brazil
[2] Univ Fed Vales Jequitinhonha & Mucuri, Fac Ciencias Biol & Saude, Dept Farm, BR-39100000 Diamantina, MG, Brazil
[3] Univ Fed Vales Jequitinhonha & Mucuri, Fac Ciencias Exactas & Sociais Aplicadas, Dept Quim, BR-39100000 Diamantina, MG, Brazil
[4] Univ Sao Paulo, Inst Fis, Sao Carlos, SP, Brazil
[5] Ctr Univ Cent Paulista, Sao Carlos, SP, Brazil
关键词
Alloy; Titanium; EIS; Polarisation; Passive films; TITANIUM-ALLOYS; PHYSIOLOGICAL SOLUTION; PASSIVE FILMS; ANODIC FILMS; BEHAVIOR; OXIDE; AL; BIOMATERIALS; RESISTANCE; STABILITY;
D O I
10.1016/j.corsci.2009.06.035
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The corrosion resistance of Ti and Ti-6Al-4V was investigated through electrochemical impedance spectroscopy, EIS, potentiodynamic polarisation curves and UV-Vis spectrophotometry. The tests were done in Hank solution at 25 degrees C and 37 degrees C. The EIS measurements were done at the open circuit potential at specific immersion times. An increase of the resistance as a function of the immersion time was observed, for Ti (at 25 degrees C and 37 degrees C), and for Ti-6Al-4V (at 25 degrees C), which was interpreted as the formation and growth of a passive film on the metallic surfaces. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2473 / 2482
页数:10
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