Growth and Characterization of Vanadium Dioxide/Niobium Doped Titanium Dioxide Heterostructures for Ultraviolet Detection

被引:10
作者
Creeden, Jason A. [1 ]
Madaras, Scott E. [1 ]
Beringer, Douglas B. [1 ]
Novikova, Irina [1 ]
Lukaszew, Rosa A. [1 ]
机构
[1] William & Mary Dept Phys, Williamsburg, VA 23187 USA
关键词
band engineering; photocurrent; quantum efficiency; thin films; vanadium dioxide; QUANTUM EFFICIENCY; OPTICAL-PROPERTIES; BLIND; FILMS; TIO2; VO2; PHOTODETECTOR; PERFORMANCE; RESPONSIVITY; TRANSITION;
D O I
10.1002/adom.201901143
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The properties of VO2/TiO2:Nb heterostructures are engineered for their potential use in ultraviolet (UV) detection and observed external quantum efficiency (EQE) exceeding 100% in both near UV (405 nm) and UV-C (254 nm) spectral regions. The proposed UV detection scheme is based on vanadium dioxide (VO2) thin films epitaxially grown on niobium doped titanium dioxide (TiO2:Nb). Such VO2/TiO2:Nb heterostructure exhibits enhanced photocurrent due to cation doping engineering in a space-charge region thus yielding favorable conditions for hole tunneling from TiO2:Nb into VO2. The heterostructure is engineered and photocurrent is optimized by varying the VO2 film thickness, reaching up to 5000% EQE for 405 nm and up to 17 000% EQE for 254 nm light, indicating that the VO2/TiO2:Nb system can be fine-tuned for efficient UV photodetection.
引用
收藏
页数:7
相关论文
共 40 条
[1]   UV/vis range photodetectors based on thin film ALD grown ZnO/Si heterojunction diodes [J].
Alkis, Sabri ;
Tekcan, Burak ;
Nayfeh, Ammar ;
Okyay, Ali Kemal .
JOURNAL OF OPTICS, 2013, 15 (10)
[2]   OPTICAL-PROPERTIES OF VANADIUM DIOXIDE AND VANADIUM PENTOXIDE THIN-FILMS [J].
CHAIN, EE .
APPLIED OPTICS, 1991, 30 (19) :2782-2787
[3]   Quantum dot-doped porous silicon metal-semiconductor metal photodetector [J].
Chou, Chia-Man ;
Cho, Hsing-Tzu ;
Hsiao, Vincent K. S. ;
Yong, Ken-Tye ;
Law, Wing-Cheung .
NANOSCALE RESEARCH LETTERS, 2012, 7
[4]   Structural and Photoelectric Properties of Epitaxially Grown Vanadium Dioxide Thin Films on c-Plane Sapphire and Titanium Dioxide [J].
Creeden, Jason A. ;
Madaras, Scott E. ;
Beringer, Douglas B. ;
Beebe, Melissa R. ;
Novikova, Irina ;
Lukaszew, R. Ale .
SCIENTIFIC REPORTS, 2019, 9 (1)
[5]  
Datskos P.C., 2015, Encycl. Opt. Photonic Eng, P451
[6]   Controlled Growth of High-Quality ZnO-Based Films and Fabrication of Visible-Blind and Solar-Blind Ultra-Violet Detectors [J].
Du, Xiaolong ;
Mei, Zengxia ;
Liu, Zhanglong ;
Guo, Yang ;
Zhang, Tianchong ;
Hou, Yaonan ;
Zhang, Ze ;
Xue, Qikun ;
Kuznetsov, Andrej Yu .
ADVANCED MATERIALS, 2009, 21 (45) :4625-4630
[7]   β-Ga2O3/p-Si heterojunction solar-blind ultraviolet photodetector with enhanced photoelectric responsivity [J].
Guo, X. C. ;
Hao, N. H. ;
Guo, D. Y. ;
Wu, Z. P. ;
An, Y. H. ;
Chu, X. L. ;
Li, L. H. ;
Li, P. G. ;
Lei, M. ;
Tang, W. H. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 660 :136-140
[8]   WSXM:: A software for scanning probe microscopy and a tool for nanotechnology [J].
Horcas, I. ;
Fernandez, R. ;
Gomez-Rodriguez, J. M. ;
Colchero, J. ;
Gomez-Herrero, J. ;
Baro, A. M. .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2007, 78 (01)
[9]   Highly Responsive Ultrathin GaS Nanosheet Photodetectors on Rigid and Flexible Substrates [J].
Hu, PingAn ;
Wang, Lifeng ;
Yoon, Mina ;
Zhang, Jia ;
Feng, Wei ;
Wang, Xiaona ;
Wen, Zhenzhong ;
Idrobo, Juan Carlos ;
Miyamoto, Yoshiyuki ;
Geohegan, David B. ;
Xiao, Kai .
NANO LETTERS, 2013, 13 (04) :1649-1654
[10]   Synthesis of Few-Layer GaSe Nanosheets for High Performance Photodetectors [J].
Hu, PingAn ;
Wen, Zhenzhong ;
Wang, Lifeng ;
Tan, Pingheng ;
Xiao, Kai .
ACS NANO, 2012, 6 (07) :5988-5994