Compilation of PZC and IEP of sparingly soluble metal oxides and hydroxides from literature

被引:391
作者
Kosmulski, Marek [1 ]
机构
[1] Tech Univ Lublin, Dept Electrochem, PL-20618 Lublin, Poland
关键词
Point of zero charge; Isoelectric point; Inert electrolyte; Surface charge; Electrokinetic potential; Alumina; Titania; Silica; SURFACE; ADSORPTION; INTERFACE; POINTS; CHARGE; MEDIA; TIO2;
D O I
10.1016/j.cis.2009.08.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The values of PZC and IEP of metal oxides reported in the literature are affected by the choice of the specimens to be studied. The specimens, which have PZC and IEP similar to the "recommended" value, are preferred by the scientists. The biased choice leads to accumulation of results for a few specimens, and the other specimens are seldom studied or they are subjected to washing procedures aimed at shift of the original IEP toward the "recommended" value. Taking the average or median of all published PZC and IEP for certain oxide as the "recommended" value leads to substantiation of previously published results due to overrepresentation of certain specimens in the sample. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:14 / 25
页数:12
相关论文
共 22 条
[1]   ADSORPTION OF POTENTIAL-DETERMINING IONS AT FERRIC OXIDE-AQUEOUS ELECTROLYTE INTERFACE [J].
ATKINSON, RJ ;
POSNER, AM ;
QUIRK, JP .
JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (03) :550-&
[2]   Heterogeneity of hydroxyl and deuteroxyl groups on the surface of TiO2 polymorphs [J].
Contescu, C ;
Popa, VT ;
Schwarz, JA .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1996, 180 (01) :149-161
[3]  
Cornell R.M., 1996, The Iron Oxide: Structure, Properties, Reactions, Occurance and Uses
[4]  
ELWAKKAD SES, 1957, J PHYS CHEM-US, V61, P494
[5]  
Feynman RP., 1974, ENG SCI, V37, P10, DOI DOI 10.1037/ARC0000076
[6]  
GASTUCHE MC, 1962, B SOC CHIM FR, P1404
[7]  
IWASAKI I, 1962, T SOC MIN ENG, V223, P113
[8]   Determination of surface potentials from the electrode potentials of a single-crystal electrode [J].
Kallay, Nikola ;
Preocanin, Tajana ;
Ivsic, Trpimir .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 309 (01) :21-27
[9]   The surface charging at low density of protonatable surface sites [J].
Kosmulski, M .
LANGMUIR, 2005, 21 (16) :7421-7426
[10]  
Kosmulski M., 2001, Chemical properties of material surfaces