Additive-free chemoselective acylation of amines and thiols

被引：21
|
作者：
Mojtahedi, Mohammad M. [1 ]
Abaee, M. Saeed
Heravi, Majid M.
Behbahani, Farahnaz K.
机构：
[1] Chem & Chem Engn Res Ctr Iran, Tehran, Iran
[2] Azzahra Univ, Sch Sci, Dept Chem, Tehran, Iran
来源：
MONATSHEFTE FUR CHEMIE | 2007年 / 138卷 / 01期
关键词：
solvent-free; acetylation; green chemistry; amines; thiols;
D O I：
10.1007/s00706-006-0564-3
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Amines with different stereoelectronic nature were efficiently acylated at room temperature using acetic anhydride in the presence of no solvent or additive. Various thiols also react equally well under the same conditions. Chemoselective protection of amines in the presence of thiols, alcohols, and phenols and of thiols in the presence of alcohols, and phenols were achieved using competitive experiments.
引用
收藏
页码：95 / 99
页数：5
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