Diaquatris(pentane-2,4-dionato-O,O′)holmium(III) monohydrate and diaquatris(pentane-2,4-dionato-O,O′)holmium(III) 4-hydroxypentan-2-one solvate dihydrate

被引：21
作者：
Kooijman, H
Nijsen, F
Spek, AL
Schip, FV
机构：
[1] Univ Utrecht, Dept Crystal & Struct Chem, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands
[2] Univ Utrecht Hosp, Dept Nucl Med, NL-3508 GA Utrecht, Netherlands
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2000年 / 56卷 / pt 2期
关键词：
D O I：
10.1107/S0108270199013566
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structures of the title compounds, [Ho(C5H7O2)(3)(H2O)(2)]. H2O and [Ho(C5H7O2)(3)(H2O)(2)]. C5H8O2. 2H(2)O, both show an eight-coordinate holmium(III) ion in a square antiprismatic configuration. The packing of these structures consists of an infinite two-dimensional network of hydrogen-bonded molecules. In both structures, the same hydrogen-bonded chain of Ho-III complexes is found.
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页码：156 / 158
页数：3
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