Extracted γ-Al2O3 from aluminum dross as a catalyst support for glycerol dry reforming reaction

被引:11
作者
Roslan, Nurul Asmawati [1 ]
Abidin, Sumaiya Zainal [1 ,2 ]
Nasir, Nur Shafiqah [1 ]
Chin, Sim Yee [1 ,2 ]
Taufiq-Yap, Y. H. [3 ,4 ]
机构
[1] Univ Malaysia Pahang, Dept Chem Engn, Coll Engn, Lebuhraya Tun Razak, Kuantan 26300, Pahang, Malaysia
[2] Univ Malaysia Pahang, Ctr Excellence Adv Res Fluid Flow CARIFF, Gambang 26300, Pahang, Malaysia
[3] Univ Putra Malaysia, Fac Sci, Catalysis Sci & Technol Res Ctr PutraCAT, Serdang 43400, Selangor, Malaysia
[4] Univ Malaysia Sabah, Chancellery Off, Kota Kinabalu 88400, Sabah, Malaysia
关键词
Aluminum Dross; gamma-Al2O3; Catalyst support; Glycerol Dry Reforming; Syngas;
D O I
10.1016/j.matpr.2020.09.390
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The utilization of extracted gamma-Al2O3 (EGA) from aluminum dross as catalyst support in glycerol dry reforming reaction (GDR) has been investigated in this current study. In this study, three main stages were evaluated which are; (i) extraction of gamma-Al2O3; (ii) preparation and characterizations of Ni-based catalyst supported on EGA and (iii) utilization of EGA as catalyst support in the GDR reaction. In the first stage, gamma-Al2O3 with the specific surface area of 156.5 m(2) g(-1) was successfully extracted before used as catalyst support. Then, 10%Ni/EGA catalyst with 108.3 m(2) g(-1) surface area was prepared by wet impregnation method. The glycerol conversion and hydrogen yield achieved in the third stage were 22% and 15% respectively. The results can be attributed to the high specific surface area of EGA, which enhanced the dispersion of Ni particles on the catalyst matrix. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码:63 / 68
页数:6
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