Mono-dispersed LiFePO4@C core-shell [001] nanorods for a high power Li-ion battery cathode

被引：30
作者：
Bao, Liang [1 ,2 ,3 ]
Xu, Gang [1 ,2 ]
Sun, Xiaolei [1 ,2 ]
Zeng, Hong [3 ]
Zhao, Ruoyu [1 ,2 ]
Yang, Xin [1 ,2 ]
Shen, Ge [1 ,2 ]
Han, Gaorong [1 ,2 ]
Zhou, Shaoxiong [3 ]
机构：
[1] Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
[2] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China
[3] China Iron & Steel Res Inst Grp, Adv Technol & Mat Co Ltd, Beijing Key Lab Energy Nanomat, Beijing 100081, Peoples R China
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2017年 / 708卷
基金：
中国国家自然科学基金;
关键词：
LiFePO4; Core-shell; Li-ion battery; RECHARGEABLE LITHIUM BATTERIES; ELECTROCHEMICAL PROPERTIES; HYDROTHERMAL SYNTHESIS; PHOSPHO-OLIVINES; NANOSHEETS; ELECTRODE; FACETS; CARBON; NANOSTRUCTURES; PERFORMANCE;
D O I：
10.1016/j.jallcom.2017.03.052
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Monodispersed LiFePO4 [001] nanorods have been successfully synthesized via a conventional hydrothermal route with Li2SO4, FeSO4 and KH2PO4 as precursors. Subsequently, in virtue of the good monodispersibility LiFePO4@C core-shell [001] nanorods are facilely prepared by employing a carbon coating process on the obtained monodispersed LiFePO4 [001] nanorods. On the basis of the experimental results, a possible formation mechanism of the monodispersed LiFePO4 [001] nanorods has been proposed. Due to the full carbon coating, size reducing in [010] and the perfect olivine crystal lattice, the LiFePO4@C core-shell [001] nanorods exhibit excellent rate capacity and stable cycle performance. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：685 / 693
页数：9
相关论文
共 40 条
  • [1] Colloidal micelles of block copolymers as nanoreactors, templates for gold nanoparticles, and vehicles for biomedical applications
    Bakshi, Mandeep Singh
    [J]. ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2014, 213 : 1 - 20
  • [2] Olivine LiFePO4 nanocrystallites embedded in carbon-coating matrix for high power Li-ion batteries
    Bao, Liang
    Li, Lingling
    Xu, Gang
    Wang, Jiangwei
    Zhao, Ruoyu
    Shen, Ge
    Han, Gaorong
    Zhou, Shaoxiong
    [J]. ELECTROCHIMICA ACTA, 2016, 222 : 685 - 692
  • [3] Hydrothermal synthesis of stamen-like LiMnPO4 nanostructures self-assembled with [001]-oriented nanorods and their application in Li-ion batteries
    Bao, Liang
    Xu, Gang
    Zeng, Hong
    Li, Lingling
    Zhao, Ruoyu
    Shen, Ge
    Han, Gaorong
    Zhou, Shaoxiong
    [J]. CRYSTENGCOMM, 2016, 18 (13): : 2385 - 2391
  • [4] Hydrothermal synthesis of flower-like LiMnPO4 nanostructures self-assembled with (010) nanosheets and their application in Li-ion batteries
    Bao, Liang
    Xu, Gang
    Wang, Jiangwei
    Zong, Hong
    Li, Lingling
    Zhao, Ruoyu
    Zhou, Shaoxiong
    Shen, Ge
    Han, Gaorong
    [J]. CRYSTENGCOMM, 2015, 17 (33): : 6399 - 6405
  • [5] Nanostructured composites of one-dimensional TiO2 and reduced graphene oxide for efficient dye-sensitized solar cells
    Cai, Haopeng
    Li, Jie
    Xu, Xiaoming
    Tang, Haolin
    Luo, Jiangshui
    Binnemans, Koen
    Fransaer, Jan
    De Vos, Dirk E.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 697 : 132 - 137
  • [6] Electron microscopy study of the LiFePO4 to FePO4 phase transition
    Chen, GY
    Song, XY
    Richardson, TJ
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (06) : A295 - A298
  • [7] LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-Ion Battery Cathode
    Choi, Daiwon
    Wang, Donghai
    Bae, In-Tae
    Xiao, Jie
    Nie, Zimin
    Wang, Wei
    Viswanathan, Vilayanur V.
    Lee, Yun Jung
    Zhang, Ji-Guang
    Graff, Gordon L.
    Yang, Zhenguo
    Liu, Jun
    [J]. NANO LETTERS, 2010, 10 (08) : 2799 - 2805
  • [8] Electronically conductive phospho-olivines as lithium storage electrodes
    Chung, SY
    Bloking, JT
    Chiang, YM
    [J]. NATURE MATERIALS, 2002, 1 (02) : 123 - 128
  • [9] Hydrothermal Synthesis of Single-Crystalline Perovskite PbTiO3 Nanosheets with Dominant (001) Facets
    Deng, Shiqi
    Xu, Gang
    Bai, Huiwen
    Li, Lingli
    Jiang, Shan
    Shen, Ge
    Han, Gaorong
    [J]. INORGANIC CHEMISTRY, 2014, 53 (20) : 10937 - 10943
  • [10] Improved electrochemical properties of LiFePO4/Cu cathode material synthesized via an optimized two-step chemical process
    Feng, Zhe-sheng
    Wang, Lu-lin
    Wang, Yan
    Chen, Jin-ju
    He, Zhen-yu
    Ji, Ding-yu
    Zhang, Yi-Xuan
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 651 : 712 - 717
1234