(±)-trans-1,2-Diaminocyclohexane crystallises as a conglomerate

被引：17

作者：

Kostyanovsky, RG ^{[1
]}

Lakhvich, FA

Philipchenko, PM

Lenev, DA

Torbeev, VY

Lyssenko, KA

机构：

[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 119991, Russia

[2] Natl Acad Sci Belarus, Inst Bioorgan Chem, Minsk 220141, BELARUS

[3] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2002年 / 04期

关键词：

D O I：

10.1070/MC2002v012n04ABEH001598

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(+/-)-trans-1,2-Diaminocyclohexane has been found to crystallise from n-hexane at -10 degreesC as a conglomerate (space group P2(1)2(1)2, Z = 2), which offers a possibility of resolving (+/-)-1 by an entrainment procedure, whereas (+/-)-1.H2SO4 forms heterochiral crystals (space group Pbca, Z = 8).

引用

页码：147 / 149

页数：3

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