Nickel/magnesium-lanthanum mixed oxide catalyst in the Kumada-coupling

被引：27

作者：

Kiss, Arpad ^{[1
]}

Hell, Zoltan ^{[1
]}

Balint, Maria ^{[2
]}

机构：

[1] Budapest Univ Technol & Econ, Dept Organ Chem & Technol, H-1521 Budapest, Hungary

[2] Balint Analit Kft, H-1116 Budapest, Hungary

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2010年 / 8卷 / 02期

关键词：

GRIGNARD-REAGENTS; ROOM-TEMPERATURE; ORGANIC HALIDES; NICKEL; TOSYLATES; SONOGASHIRA; CHARCOAL; LIGANDS;

D O I：

10.1039/b919246h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new, heterogeneous, magnesium-lanthanum mixed oxide solid base-supported nickel(II) catalyst was developed. The catalyst was used successfully in the Kumada coupling of aryl halides, especially aryl bromides. The optimal reaction conditions of the coupling were determined.

引用

页码：331 / 335

页数：5

共 30 条

[1] Air-stable PinP(O)H as preligand for palladium-catalyzed Kumada couplings of unactivated tosylates [J].

Ackermann, Lutz ;

Althammer, Andreas .

ORGANIC LETTERS, 2006, 8 (16) :3457-3460

[2]

Barbier P., 1899, CR HEBD ACAD SCI, V128, P110

[3] ALKYLATION OF HETEROARYL HALIDES BY 2-1 GRIGNARD REAGENT/CU(I) MIXTURES - SYNTHESIS OF ALKYLATED OCTAHYDRODIBENZO[B,J][1,10]PHENANTHROLINES [J].

BELL, TW ;

HU, LY ;

PATEL, SV .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (17) :3847-3850

[4]

Corriu R.J. P., 1972, J. Chem. Soc. Chem. Commun, P144

[5] A copper-free Sonogashira reaction using a Pd/MgLa mixed oxide [J].

Cwik, A ;

Hell, Z ;

Figueras, F .

TETRAHEDRON LETTERS, 2006, 47 (18) :3023-3026

[6] Palladium/magnesium-lanthanum mixed oxide catalyst in the Heck reaction [J].

Cwik, A ;

Hell, Z ;

Figueras, F .

ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (4-5) :523-530

[7] Suzuki-Miyaura cross-coupling reaction catalyzed by Pd/MgLa mixed oxide [J].

Cwik, A ;

Hell, Z ;

Figueras, F .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2005, 3 (24) :4307-4309

[8] Naphthidine di(radical cation)s-stabilized palladium nanoparticles for efficient catalytic Suzuki-Miyaura cross-coupling reactions [J].

Desmarets, Christophe ;

Omar-Amrani, Raft ;

Walcarius, Alain ;

Lambert, Jacques ;

Champagne, Benoit ;

Fort, Yves ;

Schneider, Raphael .

TETRAHEDRON, 2008, 64 (02) :372-381

[9] ACID-CATALYZED SOLVOLYSIS OF N-SULFONYL-O-ARYLHYDROXYLAMINES AND N-ACYL-O-ARYLHYDROXYLAMINES - PHENOXENIUM IONS [J].

ENDO, Y ;

SHUDO, K ;

OKAMOTO, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (23) :6393-6397

[10] Low-valent niobium-mediated double activation of C-F/C-H bonds:: Fluorene synthesis from o-arylated α,α,α-trifluorotoluene derivatives [J].

Fuchibe, K ;

Akiyama, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (05) :1434-1435

← 1 2 3 →