Oxidative dehydrogenation of alkanes over vanadium-magnesium-oxides

被引：139

作者：

Kung, HH

Kung, MC

机构：

[1] Ipatieff Laboratory, Ctr. for Catalys. and Surf. Science, Northwestern University, 2137 Sheridan Road, Evanston

来源：

APPLIED CATALYSIS A-GENERAL | 1997年 / 157卷 / 1-2期

关键词：

oxidative dehydrogenation; alkane oxidation; vanadium-magnesium-oxide; selective oxidation alkane;

D O I：

10.1016/S0926-860X(97)00028-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vanadium-magnesium-oxides are among the most selective and active catalysts for the oxidative dehydrogenation of alkane. The selectivity for dehydrogenation depends strongly on the alkane, the Mg vanadate phase, the presence of modifiers, and to a lesser extent, the method of preparation. The results of studies on these variables are reviewed and discussed with respect to the current understanding of the nature of the active site and requirements for selective dehydrogenation.

引用

页码：105 / 116

页数：12

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