Enhancement of mechanical and wear resistance performance in hexagonal boron nitride-reinforced epoxy nanocomposites

Hexagonal boron nitride (hBN), a two-dimensional nanofiller with good mechanical properties, high thermal conductivity and excellent lubrication properties, has the potential to substantially reinforce polymers to form nanocomposites with advanced properties. In this study, we successfully prepared hBN nanosheets with a thickness of a few atoms by using amine-capped aniline trimer (AT) as dispersant. Epoxy/hBN nanocomposites were prepared by curing reaction of epoxy E51, Jeffamine D230 and AT-modified hBN nanosheets, where the hBN contents were 0.5, 1, 2 and 4 wt%. An increase in contact angle of the epoxy/hBN nanocomposites was evident in the presence of hBN nanosheets, implying an increase in the hydrophobic nature of the composites. The as-prepared composites exhibited enhanced mechanical and tribological performance compared to pure epoxy resin. This effectiveness in improving the mechanical, friction and wear behavior of the epoxy composites could be attributed to the complementary action of excellent mechanical properties, lubrication and thermal conductivity of hBN nanofillers. (c) 2016 Society of Chemical Industry