Advances in C(sp2)-H/C(sp2)-H Oxidative Coupling of (Hetero)arenes Using 3d Transition Metal Catalysts

被引：41

作者：

Bansal, Sadhna ^{[1
,2
]}

Shabade, Anand B. ^{[1
,2
]}

Punji, Benudhar ^{[1
,2
]}

机构：

[1] CSIR Natl Chem Lab CSIR NCL, Div Chem Engn, Organometall Synth & Catalysis Lab, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India

[2] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2021年 / 363卷 / 08期

关键词：

3d transition metal; biaryls; C-H activation; cross-dehydrogenative coupling; (hetero)biaryls;

D O I：

10.1002/adsc.202001498

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

C-H/C-H oxidative coupling has emerged as a straightforward and powerful technique for the construction of (hetero)biaryls, with substantial application to drug discovery, agrochemicals, biology, and material sciences. Mainly aryl-aryl, aryl-heteroaryl, and heteroaryl-heteroaryl couplings via double C(sp(2))-H activation using 4d or 5d noble transition metal catalysts have been extensively studied. Considering the earth-abundant and inexpensive nature of 3d transition metals, the sustainable development of C(sp(2))-H/C(sp(2))-H oxidative coupling employing such metal catalysts has gained significant attention. In this review, we present a comprehensive overview of C(sp(2))-H/C(sp(2))-H oxidative coupling of (hetero)arenes catalyzed by 3d transition metals.

引用

页码：1998 / 2022

页数：25

共 208 条

[1]

Ackermann L, 2009, MODERN ARYLATION METHODS, P1

[2] Robust Ruthenium(II)-Catalyzed C-H Arylations: Carboxylate Assistance for the Efficient Synthesis of Angiotensin-II-Receptor Blockers [J].

Ackermann, Lutz .

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2015, 19 (01) :260-269

[3] Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C-H/Het-H Bond Functionalizations [J].

Ackermann, Lutz .

ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (02) :281-295

[4] Ni(II)-Catalyzed Oxidative Coupling between C(sp2)-H in Benzamides and C(sp3)-H in Toluene Derivatives [J].

Aihara, Yoshinori ;

Tobisu, Mamoru ;

Fukumoto, Yoshiya ;

Chatani, Naoto .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (44) :15509-15512

[5] Enantioselective Oxidative Coupling of 2-Naphthol Derivatives by Copper-(R)-1,1′-Binaphthyl-2,2′-diamine-TEMPO Catalyst [J].

Alamsetti, Santosh Kumar ;

Poonguzhali, Elamvazhuthi ;

Ganapathy, Dhandapani ;

Sekar, Govindasamy .

ADVANCED SYNTHESIS & CATALYSIS, 2013, 355 (14-15) :2803-2808

[6] Aerobic Copper-Catalyzed Organic Reactions [J].

Allen, Scott E. ;

Walvoord, Ryan R. ;

Padilla-Salinas, Rosaura ;

Kozlowski, Marisa C. .

CHEMICAL REVIEWS, 2013, 113 (08) :6234-6458

[7] Measurement of the cosmic ray proton spectrum from 40 GeV to 100 TeV with the DAMPE satellite [J].

An, Q. ;

Asfandiyarov, R. ;

Azzarello, P. ;

Bernardini, P. ;

Bi, X. J. ;

Cai, M. S. ;

Chang, J. ;

Chen, D. Y. ;

Chen, H. F. ;

Chen, J. L. ;

Chen, W. ;

Cui, M. Y. ;

Cui, T. S. ;

Dai, H. T. ;

D'Amone, A. ;

De Benedittis, A. ;

De Mitri, I. ;

Di Santo, M. ;

Ding, M. ;

Dong, T. K. ;

Dong, Y. F. ;

Dong, Z. X. ;

Donvito, G. ;

Droz, D. ;

Duan, J. L. ;

Duan, K. K. ;

D'Urso, D. ;

Fan, R. R. ;

Fan, Y. Z. ;

Fang, F. ;

Feng, C. Q. ;

Feng, L. ;

Fusco, P. ;

Gallo, V. ;

Gan, F. J. ;

Gao, M. ;

Gargano, F. ;

Gong, K. ;

Gong, Y. Z. ;

Guo, D. Y. ;

Guo, J. H. ;

Guo, X. L. ;

Han, S. X. ;

Hu, Y. M. ;

Huang, G. S. ;

Huang, X. Y. ;

Huang, Y. Y. ;

Ionica, M. ;

Jiang, W. ;

Jin, X. .

SCIENCE ADVANCES, 2019, 5 (09)

[8]

Arockiam PB, 2012, CHEM REV, V112, P5879, DOI [10.1021/cr300153j, 10.1021/cr300153J]

[9] Recent advances in cobalt-catalysed C-H functionalizations [J].

Baccalini, Alessio ;

Vergura, Stefania ;

Dolui, Pravas ;

Zanoni, Giuseppe ;

Maiti, Debabrata .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2019, 17 (48) :10119-10141

[10] Catalytic asymmetric oxidative couplings of 2-naphthols by tridentate N-ketopinidene-based vanadyl dicarboxylates [J].

Barhate, NB ;

Chen, CT .

ORGANIC LETTERS, 2002, 4 (15) :2529-2532

← 1 2 3 4 5 6 7 8 9 10 →