Enhancing the Properties of Urea Formaldehyde Wood Adhesive System Using Different Generations of Core-Shell Modifiers Based on Hydroxyl-Terminated Dendritic Poly(amidoamine)s

被引:30
作者
Essawy, Hisham A. [1 ]
Moustafa, Abd-Allah B. [1 ]
Elsayed, Nadia H. [1 ]
机构
[1] Natl Res Ctr, Dept Polymers & Pigments, Cairo 12311, Egypt
关键词
urea formaldehyde; modification; dendrimers; wood adhesive; PHYSICAL-PROPERTIES; WATER RESISTANCE; PERFORMANCE; DURABILITY; COPOLYMER; POLYMERS;
D O I
10.1002/app.30572
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Different generations of hydroxy-terminated dendritic poly(amidoamine) (Gn-OH) with ethylenediamine as a core were prepared by successive alternative addition of methylacrylate and the core up to the third generation while employing ethanolamine only in the last step of every full generation. The different generations prepared were used as modifiers for urea-formaldehyde (UF) resins. The enhanced durability and stabilizing effect of the (Gn-OH)s along with the reduced levels of free formaldehyde and improved mechanical performance of wood joints glued with the modified resins are discussed. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 115: 370-375, 2010
引用
收藏
页码:370 / 375
页数:6
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