Flexible free-standing carbon nanotube films for model lithium-ion batteries

被引：320

作者：

Chew, Sau Yen ^{[1
,2
,3
]}

Ng, See How ^{[1
,2
,3
]}

Wang, Jiazhao ^{[2
,3
]}

Novak, Petr ^{[1
]}

Krumeich, Frank ^{[4
]}

Chou, Shu Lei ^{[2
,3
]}

Chen, Jun ^{[3
,5
]}

Liu, Hua Kun ^{[2
,3
]}

机构：

[1] Paul Scherrer Inst, Electrochem Lab, CH-5232 Villigen, Switzerland

[2] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia

[3] Univ Wollongong, ARC Ctr Excellence Electromat Sci, Wollongong, NSW 2522, Australia

[4] ETH, Inorgan Chem Lab, CH-8093 Zurich, Switzerland

[5] Univ Wollongong, Intelligent Polymer Res Inst, Wollongong, NSW 2522, Australia

来源：

CARBON | 2009年 / 47卷 / 13期

基金：

澳大利亚研究理事会;

关键词：

DIRECT GROWTH; ELECTRODES; COMPOSITE; INSERTION; ANODE; STORAGE; ENERGY;

D O I：

10.1016/j.carbon.2009.06.045

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A comparative study of conductive, free-standing, binder-free flexible films made from three different types of commercial carbon nanotubes (CNTs), i.e., single-wall, double-wall, and multi-wall was carried out. The conductive CNT films were prepared by adding the CNTs to the starting dispersion of carbon black and Triton X-100, followed by a vacuum filtration technique. These films have been characterized as model free-standing, binder-free electrodes for flexible lithium-ion batteries. Our experiments revealed that films based on multi-wall CNTs (MWCNTs) are much better than single-wall and double-wall CNTs films in terms of their electrochemical performance. The flexible MWCNT electrodes show stable cycling behavior and allow up to a 10 C-rate. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：2976 / 2983

页数：8

共 38 条

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