Cationic rare-earth polyhydrido complexes:: Synthesis, structure, and catalytic activity for the cis-1,4-selective polymerization of 1,3-cyclohexadiene

被引：100

作者：

Li, Xiaofang ^{[1
]}

Baldannis, Jens ^{[1
]}

Nishiura, Masayoshi ^{[1
]}

Tardif, Olivier ^{[1
]}

Hou, Zhaomin ^{[1
]}

机构：

[1] RIKEN, Inst Phys & Chem Res, Organomet Chem Lab, Wako, Saitama 3510198, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 48期

关键词：

cations; cluster compounds; hydride ligands; polymerization; rare earths;

D O I：

10.1002/anie.200603450

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Rare activity from rare earths: Cationic rare-earth hydrides show regio- and stereoselectivity for the polymerization of 1,3-cyclohexadiene (CHD) to afford soluble crystalline cis-1,4-linked poly(CHD) that was previously unavailable. These cationic clusters are made by treating the corresponding neutral complexes with a borate activator (see scheme; Cp′: C5Me4SiMe3). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8184 / 8188

页数：5

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