Cationic rare-earth polyhydrido complexes:: Synthesis, structure, and catalytic activity for the cis-1,4-selective polymerization of 1,3-cyclohexadiene

被引：100

作者：

Li, Xiaofang ^{[1
]}

Baldannis, Jens ^{[1
]}

Nishiura, Masayoshi ^{[1
]}

Tardif, Olivier ^{[1
]}

Hou, Zhaomin ^{[1
]}

机构：

[1] RIKEN, Inst Phys & Chem Res, Organomet Chem Lab, Wako, Saitama 3510198, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 48期

关键词：

cations; cluster compounds; hydride ligands; polymerization; rare earths;

D O I：

10.1002/anie.200603450

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Rare activity from rare earths: Cationic rare-earth hydrides show regio- and stereoselectivity for the polymerization of 1,3-cyclohexadiene (CHD) to afford soluble crystalline cis-1,4-linked poly(CHD) that was previously unavailable. These cationic clusters are made by treating the corresponding neutral complexes with a borate activator (see scheme; Cp′: C5Me4SiMe3). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8184 / 8188

页数：5

共 60 条

[1]

ANWANDER R, 1996, APPL HOMOGENEOUS CAT, V2, P866

[2] Cationic alkyl complexes of the rare-earth metals: Synthesis, structure, and reactivity [J].

Arndt, S ;

Okuda, J .

ADVANCED SYNTHESIS & CATALYSIS, 2005, 347 (2-3) :339-354

[3] Mono(cyclopentadienyl) complexes of the rare-earth metals [J].

Arndt, S ;

Okuda, J .

CHEMICAL REVIEWS, 2002, 102 (06) :1953-1976

[4] Naked (C5Me5)2M cations (M = Sc, Ti, and V) and their fluoroarene complexes [J].

Bouwkamp, MW ;

Budzelaar, PHM ;

Gercama, J ;

Morales, ID ;

de Wolf, J ;

Meetsma, A ;

Troyanov, SI ;

Teuben, JH ;

Hessen, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (41) :14310-14319

[5] PREPARATION AND AROMATIZATION OF POLY-1,3-CYCLOHEXADIENE AND SUBSEQUENT CROSSLINKING .3 [J].

CASSIDY, PE ;

MARVEL, CS ;

RAY, S .

JOURNAL OF POLYMER SCIENCE PART A-GENERAL PAPERS, 1965, 3 (4PA) :1553-&

[6] Lanthanide-imido complexes and their reactions with benzonitrile [J].

Cui, D ;

Nishiura, M ;

Hou, ZM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (06) :959-962

[7]

Cui D., 2005, ANGEW CHEM, V117, P981

[8] Alternating copolymerization of cyclohexene oxide and carbon dioxide catalyzed by organo rare earth metal complexes [J].

Cui, DM ;

Nishiura, M ;

Hou, ZM .

MACROMOLECULES, 2005, 38 (10) :4089-4095

[9] Tetranuclear rare earth metal polyhydrido complexes composed of "(C5Me4SiMe3)LnH2" units.: Unique reactivities toward unsaturated C-C, C-N, and C-O bonds [J].

Cui, DM ;

Tardif, O ;

Hou, ZM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (05) :1312-1313

[10]

Edelman F, 1995, COMPREHENSIVE ORGA 2, V4, P11

← 1 2 3 4 5 6 →