In Situ UV Raman Spectroscopic Study on the Synthesis Mechanism of AlPO-5

被引：83

作者：

Fan, Fengtao ^{[1
,2
]}

Feng, Zhaochi ^{[1
]}

Sun, Keju ^{[1
]}

Guo, Meiling ^{[1
,2
]}

Guo, Qiang ^{[1
,2
]}

Song, Yu ^{[1
]}

Li, Weixue ^{[1
]}

Li, Can ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 46期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; Raman spectroscopy; reaction mechanisms; UV/Vis spectroscopy; MOLECULAR-SIEVES; ROOM-TEMPERATURE; NEUTRAL PH; CRYSTALLIZATION; ZEOLITE; ALUMINOPHOSPHATES; PHOSPHATE; ALUMINUM;

D O I：

10.1002/anie.200903601

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Piecing together the puzzle: The synthesis mechanism of AIPO-5 was studied using in situ UV Raman spectroscopy in combination with the Fenton reaction. The results reveal molecular-level insights into the role of the template in channel formation as well as the identities of the building blocks in the framework formation. © 2009 Wiley-VCH Verlag GmbH &. Co. KGaA.

引用

页码：8743 / 8747

页数：5

共 36 条

[1] One-dimensional zinc phosphates with linear chain structure [J].

Ayi, AA ;

Neeraj, S ;

Choudhury, A ;

Natarajan, S ;

Rao, CNR .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2001, 62 (08) :1481-1491

[2] THE PORE-SIZE MODIFICATION OF A LAYERED ALUMINOPHOSPHATE [AL3P4O16C9H24N3] BY RATIONAL SELECTION OF THE INTERCALATED TEMPLATE CATION [J].

BARRETT, PA ;

JONES, RH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (19) :1979-1981

[3] Monitoring the coordination of aluminium during microporous oxide crystallisation by in situ soft X-ray absorption spectroscopy [J].

Beale, Andrew M. ;

van der Eerden, Ad M. J. ;

Grandjean, Didier ;

Petukhov, Andrei V. ;

Smith, Andy D. ;

Weckhuysen, Bert M. .

CHEMICAL COMMUNICATIONS, 2006, (42) :4410-4412

[4] Amorphous microporous molecular sieves with different pore dimensions and topologies:: Synthesis, characterization and catalytic activity [J].

Corma, A ;

Díaz-Cabañas, MJ .

MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 89 (1-3) :39-46

[5] Biomimetic synthesis of microporous and mesoporous materials at room temperature and neutral pH, with application in electronics, controlled release of chemicals, and catalysis [J].

Corma, Avelino ;

Moliner, Manuel ;

Diaz-Cabanas, Maria J. ;

Serna, Pedro ;

Femenia, Beatriu ;

Primo, Jaime ;

Garcia, Hermenegildo .

NEW JOURNAL OF CHEMISTRY, 2008, 32 (08) :1338-1345

[6] Synthesis of micro- and mesoporous molecular sieves at room temperature and neutral pH catalyzed by functional analogues of silicatein [J].

Corma, Avelino ;

Diaz-Cabanas, Maria J. ;

Moliner, Manuel ;

Rodriguez, Guillermo .

CHEMICAL COMMUNICATIONS, 2006, (29) :3137-3139

[7] CONSTRAINTS ON THE MOVEMENT OF ATOMS IN THE TOTALLY SYMMETRICAL VIBRATIONS OF CRYSTAL LATTICES - LATTICE FORCE-CONSTANT CALCULATIONS FOR SODALITES [J].

CREIGHTON, JA ;

DECKMAN, HW ;

NEWSAM, JM .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (06) :2099-2101

[8] ZEOLITE AND MOLECULAR-SIEVE SYNTHESIS [J].

DAVIS, ME ;

LOBO, RF .

CHEMISTRY OF MATERIALS, 1992, 4 (04) :756-768

[9] SAXS and USAXS investigation on nanometer-scaled precursors in organic-mediated zeolite crystallization from gelating systems [J].

de Moor, PPEA ;

Beelen, TPM ;

van Santen, RA ;

Tsuji, K ;

Davis, ME .

CHEMISTRY OF MATERIALS, 1999, 11 (01) :36-43

[10] CORRELATION OF FRAMEWORK RAMAN BANDS OF ZEOLITES WITH STRUCTURE [J].

DUTTA, PK ;

SHIEH, DC ;

PURI, M .

ZEOLITES, 1988, 8 (04) :306-309

← 1 2 3 4 →