Self-Assembled Arrays of Single-Walled Metal-Organic Nanotubes

被引：117

作者：

Luo, Tzuoo-Tsair ^{[1
]}

Wu, Huang-Chun ^{[1
]}

Jao, Yu-Chen ^{[3
]}

Huang, Sheng-Ming ^{[1
]}

Tseng, Tien-Wen ^{[3
]}

Wen, Yuh-Sheng ^{[1
]}

Lee, Gene-Hsiang ^{[2
]}

Peng, Shie-Ming ^{[2
]}

Lu, Kuang-Lieh ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] Natl Taiwan Univ, Dept Chem, Taipei 107, Taiwan

[3] Natl Taipei Univ Technol, Dept Chem Engn, Taipei 106, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 50期

关键词：

crystal engineering; microporous materials; nanotubes; self-assembly; topochemistry; POROUS COORDINATION POLYMERS; HOST-GUEST CHEMISTRY; BUILDING-BLOCKS; MATERIALS SCIENCE; FRAMEWORKS; TOPOLOGY; TUBES; NETWORKS; DESIGN; NETS;

D O I：

10.1002/anie.200904501

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Chemical equation presented] Dragon's lair: A large, single-walled metal-organic nanotube (MONT) with an exterior diameter of up to 3.2 nm and an interal channel diameter of 1.4 nm is presented. The tube can be depicted as hexastranded helices consisting of three right-handed and three left-handed helical chains, and resembles a rolled-up dragon column (see picture). The MONTs are held together by alkaline ions to form unique nanotubular arrays. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.

引用

页码：9461 / 9464

页数：4

共 67 条

[1] Quantitative formation of coordination nanotubes templated by rodlike guests [J].