Ferrocenes with two carbohydrate appendages at the upper and lower rings are useful for investigating carbohydrate-carbohydrate interactions

被引:16
作者
Otsuka, Atsushi [1 ,2 ]
Sakurai, Kunihiro [1 ,2 ]
Hasegawa, Teruaki [1 ,2 ]
机构
[1] Toyo Univ, Fac Life Sci, Dept Life Sci, Itakura 3740193, Japan
[2] Toyo Univ, Bionano Elect Res Ctr, Kawagoe, Saitama 3508585, Japan
关键词
CELL-ADHESION; GOLD GLYCONANOPARTICLES; SIGNAL-TRANSDUCTION; RECOGNITION; SPECIFICITY; MONOLAYERS; ANTIGENS;
D O I
10.1039/b910534d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The conformation of ferrocene with two beta Lac appendages is changed on addition of Ca2+ and Na+, which can be ascribed to intramolecular beta Lac-beta Lac interactions mediated by these cations and the resultant stabilization of twisted rotamers along the Cp-Fe-Cp axis.
引用
收藏
页码:5442 / 5444
页数:3
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