Development of hybrid photocatalysts constructed with a metal complex and graphitic carbon nitride for visible-light-driven CO2 reduction

被引：52

作者：

Kuriki, Ryo ^{[1
]}

Maeda, Kazuhiko ^{[1
]}

机构：

[1] Tokyo Inst Technol, Sch Sci, Dept Chem, Meguro Ku, 2-12-1-NE-2 Ookayama, Tokyo 1528550, Japan

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2017年 / 19卷 / 07期

基金：

日本科学技术振兴机构;

关键词：

BINUCLEAR RUTHENIUM(II) COMPLEX; ULTRAFAST ELECTRON-TRANSFER; HIGH TURNOVER FREQUENCY; PHOTOCHEMICAL REDUCTION; HYDROGEN EVOLUTION; HIGHLY EFFICIENT; FORMIC-ACID; HOMOGENEOUS CATALYSTS; THIN-FILMS; ELECTROCHEMICAL REDUCTION;

D O I：

10.1039/c6cp07973c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photocatalytic CO2 reduction with visible light has long been studied as a potential means to address the problems of global warming and the depletion of fossil fuels. Hybrid systems that consist of a metal complex and a particulate semiconductor are expected to be promising because of the excellent electrochemical (and/or photocatalytic) ability of metal complexes for CO2 reduction and the high efficiency of semiconductors for water oxidation. However, a satisfactory system has not been developed to date. Our group has been developing such hybrid materials for visible-light-driven CO2 reduction. This Perspective highlights our recent progress in the development of metal-complex/semiconductor hybrid materials for photocatalytic CO2 reduction with a focus on graphitic carbon nitride as the semiconductor component.

引用

页码：4938 / 4950

页数：13

共 79 条

[1] Solar CO2 reduction using H2O by a semiconductor/metal-complex hybrid photocatalyst: enhanced efficiency and demonstration of a wireless system using SrTiO3 photoanodes [J].

Arai, Takeo ;

Sato, Shunsuke ;

Kajino, Tsutomu ;

Morikawa, Takeshi .

ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (04) :1274-1282

[2] Ultrafast electron transfer dynamics from molecular adsorbates to semiconductor nanocrystalline thin films [J].

Asbury, JB ;

Hao, E ;

Wang, YQ ;

Ghosh, HN ;

Lian, TQ .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (20) :4545-4557

[3] Bridge length-dependent ultrafast electron transfer from Re polypyridyl complexes to nanocrystalline TiO2 thin films studied by femtosecond infrared spectroscopy [J].

Asbury, JB ;

Hao, EC ;

Wang, YQ ;

Lian, TQ .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (50) :11957-11964

[4] Electroreduction of CO, catalyzed by polymeric [Ru(bpy)(CO)2]n films in aqueous media:: parameters influencing the reaction selectivity [J].

Chardon-Noblat, S ;

Deronzier, A ;

Ziessel, R ;

Zsoldos, D .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 444 (02) :253-260

[5] Selective synthesis and electrochemical behavior of trans(Cl)- and cis(Cl)-[Ru(bpy)(CO)(2)Cl-2] complexes (bpy = 2,2'-bipyridine). Comparative studies of their electrocatalytic activity toward the reduction of carbon dioxide [J].

ChardonNoblat, S ;

Deronzier, A ;

Ziessel, R ;

Zsoldos, D .

INORGANIC CHEMISTRY, 1997, 36 (23) :5384-5389

[6] Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center [J].

Chen, Lingjing ;

Guo, Zhenguo ;

Wei, Xi-Guang ;

Gallenkamp, Charlotte ;

Bonin, Julien ;

Anxolabehere-Mallart, Elodie ;

Lau, Kai-Chung ;

Lau, Tai-Chu ;

Robert, Marc .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (34) :10918-10921

[7] ELECTROCATALYTIC REDUCTION OF CARBON-DIOXIDE WITH MONO(BIPYRIDINE)CARBONYLRUTHENIUM COMPLEXES IN SOLUTION OR AS POLYMERIC THIN-FILMS [J].

COLLOMBDUNANDSAUTHIER, MN ;

DERONZIER, A ;

ZIESSEL, R .

INORGANIC CHEMISTRY, 1994, 33 (13) :2961-2967

[8] Metal-free photocatalytic degradation of 4-chlorophenol in water by mesoporous carbon nitride semiconductors [J].

Cui, Yanjuan ;

Huang, Jianhui ;

Fu, Xianzhi ;

Wang, Xinchen .

CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (07) :1396-1402

[9] Porous structure dependent photoreactivity of graphitic carbon nitride under visible light [J].

Dong, Guohui ;

Zhang, Lizhi .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (03) :1160-1166

[10] ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].

FUJISHIMA, A ;

HONDA, K .

NATURE, 1972, 238 (5358) :37-+

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