Synthesis of catalytically active diene and cyclopentadienyl rhodium halide complexes

被引：18
作者：
Kolos, Andrey V. [1 ]
Perekalin, Dmitry S. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2021年 / 31卷 / 01期
基金：
俄罗斯科学基金会;
关键词：
rhodium; catalysis; diene; cyclopentadienyl; half-sandwich complexes; ligand structure; C-H ACTIVATION; CATALYZED ASYMMETRIC 1,4-ADDITION; X-RAY-STRUCTURE; METAL-COMPLEXES; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURES; ELECTRONIC-STRUCTURE; STEERING LIGANDS; HIGH-PERFORMANCE; ARENE COMPLEXES;
D O I：
10.1016/j.mencom.2021.01.001
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Diene and cyclopentadienyl rhodium halides are very often used as catalysts for various transformations. Herein we analyze the advantages and limitations of classical and more recent synthetic methods for the preparation of these catalysts with a focus on the compounds with chiral ligands.
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页码：1 / 7
页数：7
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