A new fluorescent chemosensor for Fe3+ and Cu2+ based on calix[4]arene

被引：141
|
作者：
Liu, JM [1 ]
Zheng, QY [1 ]
Yang, JL [1 ]
Chen, CF [1 ]
Huang, ZT [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 50期
基金：
中国国家自然科学基金;
关键词：
calix[4]arene; chemosensor; fluorescent spectra; iron; copper;
D O I：
10.1016/S0040-4039(02)02265-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel fluorescent compound derived from calixarene which possesses two 3-alkoxy-2-naphthoic acid moieties has been synthesized in moderate yield. In H2O/CH3OH (1:1), its fluorescent intensity was quenched sharply in the presence of Cu2+ or Fe3+, and the degree of quenching was related to the pH of the solution. Other metal ions, such as Co2+, Ni2+, Zn2+, Mn2+, Mg2+ and Ba2+ did not affect its fluorescent spectra. This research may provide a new fluorescent probe for Cu2+ and Fe3+. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：9209 / 9212
页数：4
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