Enantioselective electrophilic fluorination in ionic liquids

被引：41
作者：
Baudequin, C [1 ]
Plaquevent, JC [1 ]
Audouard, C [1 ]
Cahard, D [1 ]
机构：
[1] Univ Rouen, IRCOF, UMR 6014, F-76821 Mont St Aignan, France
来源：
GREEN CHEMISTRY | 2002年 / 4卷 / 06期
关键词：
D O I：
10.1039/b208817g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
It has been demonstrated that enantioselective electrophilic fluorination performed by means of N-fluorocinchonium salts in ionic liquids presents substantial advantages over the use of classical solvents.
引用
收藏
页码：584 / 586
页数：3
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共 37 条
  • [1] Ionic liquid-phase asymmetric catalytic hydrogenation: hydrogen concentration effects on enantioselectivity
    Berger, A
    de Souza, RF
    Delgado, MR
    Dupont, J
    [J]. TETRAHEDRON-ASYMMETRY, 2001, 12 (13) : 1825 - 1828
  • [2] Asymmetric hydrogenation and catalyst recycling using ionic liquid and supercritical carbon dioxide
    Brown, RA
    Pollet, P
    McKoon, E
    Eckert, CA
    Liotta, CL
    Jessop, PG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (06) : 1254 - 1255
  • [3] Design, synthesis, and evaluation of a novel class of enantioselective electrophilic fluorinating agents:: N-fluoro ammonium salts of cinchona alkaloids (F-CA-BF4)
    Cahard, D
    Audouard, C
    Plaquevent, JC
    Roques, N
    [J]. ORGANIC LETTERS, 2000, 2 (23) : 3699 - 3701
  • [4] N-Fluorocinchonidinium tetrafluoroborate F-CD-BF4:: purification and structure elucidation of this novel enantioselective electrophilic fluorinating agent
    Cahard, D
    Audouard, C
    Plaquevent, JC
    Toupet, L
    Roques, N
    [J]. TETRAHEDRON LETTERS, 2001, 42 (10) : 1867 - 1869
  • [5] Asymmetric fluorination of enolates with nonracemic N-fluoro-2,10-camphorsultams
    Davis, FA
    Zhou, P
    Murphy, CK
    Sundarababu, G
    Qi, HY
    Han, W
    Przeslawski, RM
    Chen, BC
    Carroll, PJ
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (07) : 2273 - 2280
  • [6] ASYMMETRIC FLUORINATION OF ENOLATES WITH N-FLUORO 2,10-(3,3-DICHLOROCAMPHORSULTAM)
    DAVIS, FA
    ZHOU, P
    MURPHY, CK
    [J]. TETRAHEDRON LETTERS, 1993, 34 (25) : 3971 - 3974
  • [7] NEW FLUORINATING REAGENTS .1. THE 1ST ENANTIOSELECTIVE FLUORINATION REACTION
    DIFFERDING, E
    LANG, RW
    [J]. TETRAHEDRON LETTERS, 1988, 29 (47) : 6087 - 6090
  • [8] Ionic liquids. Green solvents for the future
    Earle, MJ
    Seddon, KR
    [J]. PURE AND APPLIED CHEMISTRY, 2000, 72 (07) : 1391 - 1398
  • [9] Enantioselective cyclopropanation reactions in ionic liquids
    Fraile, JM
    García, JI
    Herrerías, CI
    Mayoral, JA
    Carrié, D
    Vaultier, M
    [J]. TETRAHEDRON-ASYMMETRY, 2001, 12 (13) : 1891 - 1894
  • [10] A novel system consisting of Rh-DuPHOS and ionic liquid for asymmetric hydrogenations
    Guernik, S
    Wolfson, A
    Herskowitz, M
    Greenspoon, N
    Geresh, S
    [J]. CHEMICAL COMMUNICATIONS, 2001, (22) : 2314 - 2315
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