Micrometer-Sized Organic Single Crystals, Anisotropic Transport, and Field-Effect Transistors of a Fused-Ring Thienoacene

被引:100
作者
Li, Rongjin [1 ,3 ]
Jiang, Lang [1 ,3 ]
Meng, Qing [1 ,3 ]
Gao, Jianhua [1 ]
Li, Hongxiang [1 ,2 ]
Tang, Qingxin [1 ]
He, Meng [4 ]
Hu, Wenping [1 ]
Liu, Yunqi [1 ]
Zhu, Daoben [1 ]
机构
[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
[3] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[4] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
PHYSICAL VAPOR GROWTH; HIGH-PERFORMANCE; CHARGE-TRANSPORT; SEMICONDUCTOR; RIBBONS;
D O I
10.1002/adma.200900934
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hexagonal micrometer-sized organic single crystals of a fused-ring thienoacene are grown controllably by physical vapor transport over a large area. A "two-dimensional organic-ribbon mask" technique is developed to fabricate organic field-effect transistors based on an individual microcrystal. The accomplished transistors exhibit mobility as high as 1.8 cm(2)V(-1)s(-1) with on/off ratios of typically > 10(7).
引用
收藏
页码:4492 / +
页数:5
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