An experimental investigation on the rate of CO2 absorption into aqueous methyldiethanolamine solutions

被引:33
|
作者
Benamor, Abdelbaki
Aroua, Mohamed Kheireddine [1 ]
机构
[1] Univ Malaya, Dept Chem Engn, Kuala Lumpur 50603, Malaysia
[2] Univ Nottingham, Sch Chem & Environm Engn, Selangor 43500, Malaysia
关键词
reaction; methyldiethanolamine; carbon dioxide; kinetics; absorption;
D O I
10.1007/s11814-007-5003-6
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper, the CO2 absorption rates into aqueous solutions of Methydiethanolamine (MDEA) at various concentrations of 1, 2, 3 and 4 M and temperatures varying from 293 to 323 K were measured by using a laboratory stirred reactor. The kinetics experiments were conducted under a pseudo first order regime. The data were analyzed by means of chemical absorption theory and the kinetic parameters associated with the reaction, such as the reaction order and the reaction rate constants, were evaluated. The effect of temperature on the reaction rate constant was assessed and the activation energy was evaluated at about 44.12 kJoule/mol.
引用
收藏
页码:16 / 23
页数:8
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