Engineering interfacial charge-transfer by phase transition realizing enhanced photocatalytic hydrogen evolution activity

被引:28
作者
Wu, Chuanqiang [1 ]
Fang, Qi [1 ]
Liu, Qin [1 ]
Liu, Daobin [1 ]
Wang, Changda [1 ]
Xiang, Ting [1 ]
Khalil, Adnan [1 ]
Chen, Shuangming [1 ]
Song, Li [1 ]
机构
[1] Univ Sci & Technol China, CAS Ctr Excellence Nanosci, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China
关键词
GRAPHITIC CARBON NITRIDE; MOS2; NANOSHEETS;
D O I
10.1039/c6qi00596a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Thin, planar nanojunctions between layered 2H/1T-MoS2 and graphitic C3N4 (g-C3N4) were fabricated and 1T phase nanojunctions allowed faster photogenerated electrons across the junction interfaces to facilitate hydrogen evolution. This research represents a proof of concept for the rational fabrication of thin 1T phase interfacial junctions and the importance of the 1T phase for further improving the HER perfomance.
引用
收藏
页码:663 / 667
页数:5
相关论文
共 27 条
[1]  
Acerce M, 2015, NAT NANOTECHNOL, V10, P313, DOI [10.1038/NNANO.2015.40, 10.1038/nnano.2015.40]
[2]   Insight into Electrocatalysts as Co-catalysts in Efficient Photocatalytic Hydrogen Evolution [J].
Bi, Wentuan ;
Zhang, Lei ;
Sun, Zhongti ;
Li, Xiaogang ;
Jin, Tao ;
Wu, Xiaojun ;
Zhang, Qun ;
Luo, Yi ;
Wu, Changzheng ;
Xie, Yi .
ACS CATALYSIS, 2016, 6 (07) :4253-4257
[3]   Photoluminescence from Chemically Exfoliated MoS2 [J].
Eda, Goki ;
Yamaguchi, Hisato ;
Voiry, Damien ;
Fujita, Takeshi ;
Chen, Mingwei ;
Chhowalla, Manish .
NANO LETTERS, 2011, 11 (12) :5111-5116
[4]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+
[5]   Layered Nanojunctions for Hydrogen-Evolution Catalysis [J].
Hou, Yidong ;
Laursen, Anders B. ;
Zhang, Jinshui ;
Zhang, Guigang ;
Zhu, Yongsheng ;
Wang, Xinchen ;
Dahl, Soren ;
Chorkendorff, Ib .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (13) :3621-3625
[6]   Solution-phase epitaxial growth of noble metal nanostructures on dispersible single-layer molybdenum disulfide nanosheets [J].
Huang, Xiao ;
Zeng, Zhiyuan ;
Bao, Shuyu ;
Wang, Mengfei ;
Qi, Xiaoying ;
Fan, Zhanxi ;
Zhang, Hua .
NATURE COMMUNICATIONS, 2013, 4
[7]  
Kappera R, 2014, NAT MATER, V13, P1128, DOI [10.1038/NMAT4080, 10.1038/nmat4080]
[8]   Smart Hybrids of Zn2GeO4 Nanoparticles and Ultrathin g-C3N4 Layers: Synergistic Lithium Storage and Excellent Electrochemical Performance [J].
Li, Xiaodan ;
Feng, Yi ;
Li, Meicheng ;
Li, Wei ;
Wei, Hao ;
Song, Dandan .
ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (44) :6858-6866
[9]   Fabrication of inorganic-organic core-shell heterostructure: novel CdS@g-C3N4 nanorod arrays for photoelectrochemical hydrogen evolution [J].
Li, Yuangang ;
Wei, Xiaoliang ;
Li, Huajing ;
Wang, Rongrong ;
Feng, Juan ;
Yun, Hui ;
Zhou, Anning .
RSC ADVANCES, 2015, 5 (19) :14074-14080
[10]   Tunable Photodeposition of MoS2 onto a Composite of Reduced Graphene Oxide and CdS for Synergic Photocatalytic Hydrogen Generation [J].
Li, Yuexiang ;
Wang, Hao ;
Peng, Shaoqin .
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (34) :19842-19848