1D and 2D Cobalt(II) coordination polymers with dipicolinic acid ligands and photocatalytic CO2 reduction

被引：0

作者：

Zhu, Han ^{[1
]}

Xu, Quanqing ^{[1
]}

Kou, Junfeng ^{[1
]}

Liu, Fengyi ^{[1
]}

机构：

[1] Yunnan Normal Univ, Coll Chem & Chem Engn, Kunming 650500, Yunnan, Peoples R China

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2021年 / 60卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Dipicolinic acid; Cobalt(II) coordination polymers; Photocatalytic CO2 reduction; VISIBLE-LIGHT; CARBON-DIOXIDE; HIGHLY EFFICIENT; PHOTOCHEMICAL REDUCTION; METAL COMPLEX; IRON; CATALYST; MONOXIDE; METHANOL; SYSTEMS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1D and 2D cobalt(II) coordination polymers, [Co(2,3-dpc)(H2O)(2)](n) (1), [Co(2,5-dpc)(H2O)(3)](n) (2) and [Co(3,5-dpc)(H2O)(2)](n) (3) (dpc = dipicolinic acid dianion) have been successfully synthesized by reaction of dipicolinic acid ligands with CoF2 in aqueous methanolic solution under hydrothermal conditions. High resolution mass spectroscopy investigation reveals the forming process of CO during the photocatalytic CO2 reduction and the plausible mechanisms are proposed.

引用

页码：356 / 360

页数：5

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