Molecular tectonics: design of 2-D networks by simultaneous use of charge-assisted hydrogen and coordination bonds

被引:26
作者
Carpanese, Cristina [1 ]
Ferlay, Sylvie [1 ]
Kyritsakas, Nathalie [1 ]
Henry, Marc [2 ]
Hosseini, Mir Wais [1 ]
机构
[1] Univ Strasbourg, Chim Coordinat Organ Lab, CNRS, UMR 7140,Inst Le Bel, F-67000 Strasbourg, France
[2] Univ Strasbourg, Lab Chim Mol Etat Solide, CNRS, UMR 7140,Inst Le Bel, F-67000 Strasbourg, France
关键词
SOLID-STATE; BUILDING-BLOCKS; COMPLEXES; POLYMORPHISM; RECOGNITION; GENERATION; FRAMEWORKS; CHEMISTRY; NETS;
D O I
10.1039/b908496g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Using a combination of charge-assisted H- and coordination-bonds, a tetra component system composed of a dicationic and a dianionic organic tecton, Ag+ cation and XF6- (X = P, As, Sb) anion behaves as planned and leads to the formation of 2-D isostructural networks for which the energetic contributions of the two recognition events dominate the construction process.
引用
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页码:6786 / 6788
页数:3
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