Molecular tectonics: design of 2-D networks by simultaneous use of charge-assisted hydrogen and coordination bonds

被引：26

作者：

Carpanese, Cristina ^{[1
]}

Ferlay, Sylvie ^{[1
]}

Kyritsakas, Nathalie ^{[1
]}

Henry, Marc ^{[2
]}

Hosseini, Mir Wais ^{[1
]}

机构：

[1] Univ Strasbourg, Chim Coordinat Organ Lab, CNRS, UMR 7140,Inst Le Bel, F-67000 Strasbourg, France

[2] Univ Strasbourg, Lab Chim Mol Etat Solide, CNRS, UMR 7140,Inst Le Bel, F-67000 Strasbourg, France

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 44期

关键词：

SOLID-STATE; BUILDING-BLOCKS; COMPLEXES; POLYMORPHISM; RECOGNITION; GENERATION; FRAMEWORKS; CHEMISTRY; NETS;

D O I：

10.1039/b908496g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using a combination of charge-assisted H- and coordination-bonds, a tetra component system composed of a dicationic and a dianionic organic tecton, Ag+ cation and XF6- (X = P, As, Sb) anion behaves as planned and leads to the formation of 2-D isostructural networks for which the energetic contributions of the two recognition events dominate the construction process.

引用

页码：6786 / 6788

页数：3

共 14 条

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[14] Molecular tectonics: generation and structural studies on 1-and 2D coordination networks based on a meta-cyclophane in 1,3-alternate conformation bearing four pyrazolyl units and cobalt, zinc and copper cations
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