Pd-Catalyzed regioselective hydroesterification of 2-allylphenols to seven-membered lactones without external CO gas

被引：12

作者：

Chang, Wenju ^{[1
]}

Li, Jingfu ^{[1
]}

Ren, Wenlong ^{[1
]}

Shi, Yian ^{[1
,2
,3
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, Ctr Multimol Organ Chem, State Key Lab Coordinat Chem,Collaborat Innovat C, Nanjing 210093, Jiangsu, Peoples R China

[2] Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

[3] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 11期

基金：

中国国家自然科学基金;

关键词：

BAEYER-VILLIGER OXIDATION; MEDIUM-RING LACTONES; METHYL-FORMATE; CYCLOCARBONYLATION REACTIONS; CARBON-MONOXIDE; ASYMMETRIC HYDROSILYLATION; IMIDAZOLE DERIVATIVES; SELECTIVE SYNTHESIS; EFFICIENT SYNTHESIS; EPSILON-LACTONES;

D O I：

10.1039/c5ob02663f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Effective Pd-catalyzed regioselective hydroesterification of 2-allylphenols with phenyl formate is described. A variety of seven-membered lactones can be obtained in good yields under mild conditions without the use of toxic CO gas.

引用

页码：3047 / 3052

页数：6

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