Structural Features of Monomeric Octahedral Monooxo d2-Rhenium(V) Complexes [ReO(Ln)2(Lmono)] with Oxygen Atoms of Bidentate Chelate O,N Ligands (Ln): 1. Complexes with Five-Membered Chelate Rings ReNC2O

被引：3

作者：

Sergienko, V. S. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[2] Russian Acad Sci, All Russian Inst Sci & Tech Informat, Moscow 125190, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2019年 / 64卷 / 03期

关键词：

crystal structure; X-ray diffraction; octahedral d(2)-Re monooxo complexes; bidentate chelate (O; N); ligands; RHENIUM(V) OXO COMPLEXES; TD-DFT CALCULATIONS; OXORHENIUM(V) COMPLEXES; SPECTROSCOPIC CHARACTERIZATION; CATALYTIC APPLICATION; CRYSTAL-STRUCTURES; X-RAY; COORDINATION; TRANS; ACIDS;

D O I：

10.1134/S0036023619030185

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structural features of 14 mononuclear d(2)-Re(V) octahedral monooxo complexes with mono-charged oxygen atoms of bidentate chelate (O,N) ligands ((L)n) of the general formula [ReO(L-n)(2)(L-mono)] (L-mono is a monodentate ligand) containing five-membered chelate rings ReNC2O are discussed. The O(L-n) atoms are in the trans positions to the O(oxo) ligands.

引用

页码：317 / 322

页数：6

共 42 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2] Complexes of oxorhenium(V) with aromatic 2-amino-alcohols [J].

Bandoli, G ;

Dolmella, A ;

Gerber, TIA ;

Mpinda, D ;

Perils, J ;

Du Preez, JGH .

JOURNAL OF COORDINATION CHEMISTRY, 2002, 55 (07) :823-833

[3] Solvent dependency of substitution reactions of oxorhenium(V) complexes. The crystal structures of trans-dichloro (N-phenylsalicylideneiminato)-triphenylphosphineoxorhenium(V) and chloro(8-oxyquinoline) [(2-oxymethylene-6-hydroxymethyl)-pyridine]oxorhenium(V) [J].

Bandoli, G ;

Gatto, S ;

Gerber, TIA ;

Perils, J ;

DuPreez, JGH .

JOURNAL OF COORDINATION CHEMISTRY, 1996, 39 (3-4) :299-311

[4] A novel dirhenium(III) complex with bridging picolinate and methoxide ligands from the reaction between cis-Re2(μ-O2CCH3)2Cl4(H2O)2 and picolinic acid [J].

Chattopadhyay, S ;

Fanwick, PE ;

Walton, RA .

INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (11) :1358-1361

[5] The syntheses and structures of '3+2' and '2+2+1' oxorhenium mixed-ligand complexes employing 8-hydroxy-5-nitroquinoline as the bidentate N,O donor ligand [J].

Chen, XY ;

Femia, FJ ;

Babich, JW ;

Zubieta, J .

INORGANICA CHIMICA ACTA, 2000, 308 (1-2) :80-90

[6]

Delofire A., 1999, J CHEM SOC DA, V2897

[7] The coordination mode of 3-hydroxypicolinic acid in oxorhenium(V) complexes.: Crystal and molecular structures of (n-Bu4N)[ReOCl3(HO-C5H3N-CO2)] and [ReOCl(HO-C5H3N-CO2)2] [J].

Gatto, S ;

Gerber, TIA ;

Bandoli, G ;

Perils, J ;

du Preez, JGH .

INORGANICA CHIMICA ACTA, 1998, 269 (02) :235-240

[8] The coordination of 2-(hydroxymethyl)pyridine to oxorhenium(V).: Synthesis and crystal structure of [ReOCl(C5H4N-CH2O)2] [J].

Gerber, TIA ;

Luzipo, DG ;

Mayer, P .

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2005, 35 (01) :39-41

[9] Synthesis and crystal structure of [ReO(AHP)2(PPh3)]Cl (HAHP=2-amino-3-hydroxypyridine):: A novel cationic monooxorhenium(V) complex [J].

Gerber, TIA ;

Luzipo, D ;

Mayer, P .

JOURNAL OF COORDINATION CHEMISTRY, 2004, 57 (16) :1419-1423

[10]

Griffith F., 1968, J CHEM SOC A, V379

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